Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1995-08-21
1996-06-04
Dees, Jose G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
560148, 560161, 564186, 564224, C07C26100
Patent
active
055234631
ABSTRACT:
A process for the manufacture of N-protected .alpha.-aminoketones and N-protected .alpha.-aminoalcohols of the formula ##STR1## wherein X is halogen, one of Q.sup.1 and Q.sup.2 is hydrogen and the other is hydroxy or Q.sup.1 and Q.sup.2 together are oxo, R.sup.1 is an amino protecting group and R.sup.2 is hydrogen or the characterizing group of an .alpha.-aminocarboxylic acid,
starting from the corresponding lower alkyl N-protected .alpha.-aminocarboxylates via corresponding lower alkyl N-silyl protected .alpha.-aminocarboxylates.
REFERENCES:
patent: 5157041 (1992-10-01), Handa et al.
patent: 5196438 (1993-03-01), Martin et al.
patent: 5430041 (1995-07-01), Martin et al.
patent: 5451678 (1995-09-01), Parkes et al.
patent: 5455353 (1995-10-01), Hilpert
Bark Samuel
Dees Jos,e G.
Epstein William H.
Gould Gerge M.
Hoffmann-La Roche Inc.
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