Method of producing ferrous sulfate heptahydrate

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Iron group metal

Reexamination Certificate

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C423S150300, C423S558000, C423SDIG022

Reexamination Certificate

active

07097816

ABSTRACT:
In a method of producing ferrous sulfate heptahydrate, ferrous sulfate monohydrate is converted in a crystallization reactor in the presence of water into ferrous sulfate heptahydrate as crystallized product, and water is subsequently isolated from the ferrous sulfate heptahydrate. Ferrous sulfate monohydrate is obtained from a pickling solution containing ferrous chloride, hydrochloric acid and water and reacted in a precipitating reactor in the presence of excess sulfuric acid to form ferrous sulfate monohydrate and hydrochloric acid. The ferrous sulfate monohydrate is then dehumidified and converted in a crystallization reactor in the presence of excess water into ferrous sulfate heptahydrate.

REFERENCES:
patent: 3100727 (1963-08-01), Labergere
patent: 3340015 (1967-09-01), Karsay
patent: 3635664 (1972-01-01), Morimoto
patent: 4222997 (1980-09-01), Beecher
patent: 4382916 (1983-05-01), Beecher
patent: 5417955 (1995-05-01), Connolly
patent: 2002/0005210 (2002-01-01), Olsen et al.
patent: 2003/0026746 (2003-02-01), Olsen et al.
patent: 251495 (1926-05-01), None
DERWENT Abstract accession No. 1993-019072, for DE 4122920 A1, published Jan. 1993.
DERWENT Abstract accession No. 1977-88946Y, for JP 52130497, published Nov. 1977.
EP search report for EP 04 01 4637, dated Nov. 24, 2004.

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