Method of producing dense refractory oxide coatings on metallic

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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148 28, 148 315, 148 38, 376457, 376900, 208 48R, 252317, 252466B, 252466PT, 4232132, 4232135, 427372A, 427380, 427419A, 427419B, 428469, 4273977, 4274192, 4274193, B01J 2108, B01J 2310, B01J 2356, B32B 1518

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active

042972469

ABSTRACT:
The invention is concerned with providing substrates with coatings obtainable from sols, for example to protect the substrate (such as in nuclear reactors or hydrocarbon cracking plant) or to provide a carrier for catalytically active material.
Hitherto, coatings obtained from sols have had a high porosity and high surface area so that they have not been entirely satisfactory for the above applications.
In the invention, dense, low-porosity coatings are provided by contacting the substrate with a sol of refractory material (e.g. CeO.sub.2 or SiO.sub.2) convertible to a gel of density at least 40% of the theoretical density of the refractory material, and converting the sol to the gel. Optionally, the gel may be converted to a ceramic coating by firing.

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patent: 4096095 (1978-06-01), Cairns

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