Method of producing amines from alcohols, aldehydes, ketones and

Details Method of producing amines from alcohols, aldehydes, ketones and Method of producing amines from alcohols, aldehydes, ketones and

1977-08-29

1979-05-01

Shaver, Paul F.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260585C, 260583R, C07C 8502

Patent

active

041523539

ABSTRACT:
A method of producing amines, the method comprising contacting at reactive conditions at least one alcohol, aldehyde or ketone or a mixture thereof with an aminating agent in the presence of a catalyst, is improved by employing as the catalyst a composition comprising nickel, copper and a third component selected from the group consisting of iron, zinc, zirconium and mixtures thereof. For example, polypropylene glycol is quantitatively aminated by contacting it with ammonia at about 175.degree. C. and in the presence of a catalyst comprising (metal basis) 30 mole percent nickel, 63 mole percent copper and about 7 mole percent iron.

REFERENCES:
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patent: 3128311 (1964-04-01), Shirley et al.
patent: 3152998 (1964-10-01), Moss
patent: 3347926 (1967-10-01), Zech
patent: 3390184 (1968-06-01), Moss et al.
patent: 3520933 (1970-07-01), Adam et al.
patent: 3654370 (1972-04-01), Yeakey et al.
Pasek et al., "Ind. Eng. Chem. Prod. Res. Develop.", vol. 11, No. 3, 5/1/72.

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