Method of producing aliphatic and cycloaliphatic diols by cataly

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568811, 568830, 568861, 568864, 568884, 568885, C07C 29141

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050307711

ABSTRACT:
A method of producing aliphatic and cycloaliphatic diols by catalytic hydrogenation of dicarboxylic acid esters by the use of a copper chromite catalyst in which the copper content (calculated as CuO) is 40-47 wt. %, and the chromium content (calculated as Cr.sub.2 O.sub.3) is 40-47 wt. %, and barium is also present in the amount of up to 10 wt. % (calculated as BaO) under mild temperature and pressure conditions is disclosed. The method produces diols without the formation of high boiling materials and does not require purification of the product diols by overhead distillation.

REFERENCES:
patent: 2137407 (1938-11-01), Lazier
patent: 2884450 (1959-04-01), Holmquist
patent: 4268695 (1981-05-01), Lange et al.
patent: 4361710 (1982-11-01), Weitz et al.
patent: 4584419 (1986-04-01), Sharif
patent: 4652685 (1987-03-01), Cawse et al.
patent: 4751334 (1988-06-01), Turner

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