Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1994-03-10
1995-10-03
Dees, Jose G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
C07C 69675
Patent
active
054553725
ABSTRACT:
A glycolic acid ester is produced by hydrogenating an oxalic acid diester of the formula, (COOR).sub.2, wherein R is a C.sub.1-6 alkyl group, with hydrogen in the presence of a solid catalyst comprising, for example, copper and silver metals carried on a solid carrier, and in the additional presence of an aliphatic alcohol, and collecting the resultant glycolic acid ester from the reaction mixture by distillation, preferably in the presence of an ester of a C.sub.3-12 dicarboxylic acid.
REFERENCES:
patent: 4112245 (1978-09-01), Zehner et al.
patent: 4409395 (1983-10-01), Miyazaki et al.
patent: 4585890 (1986-04-01), Miyazaki et al.
Fukuda Yasunori
Hirai Koichi
Nakamura Yasuo
Dees Jos,e G.
Frazier Barbara S.
Ube Industries Ltd.
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