Method of preparing storage phosphors from dedicated precursors

Compositions – Inorganic luminescent compositions – Compositions containing halogen; e.g. – halides and oxyhalides

Reexamination Certificate

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Reexamination Certificate

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11049249

ABSTRACT:
In a method for producing CsX:Eu stimulable phosphors and screens or panels provided with said phosphors as powder phosphors or vapor deposited needle-shaped phosphors suitable for use in image forming methods for recording and reproducing images of objects made by high energy radiation, said CsX:Eu stimulable phosphors are essentially free from oxygen in their crystal structure, wherein X represents a halide selected from the group consisting of Br, Cl and combinations thereof; and wherein the method further comprises the steps of mixing CsX with a compound or combinations of compounds having as a composition CsxEuyX′x+αy, wherein the ratio of x to y exceeds a value of 0.25, wherein α≧2 and wherein X′ is a halide selected from the group consisting of Cl, Br and I and combinations thereof; heating said mixture at a temperature above 450° C.; cooling said mixture, and, optionally, annealing and recovering said CsX:Eu phosphor.

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