Method of preparing primary aliphatic mercaptans

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260609D, C07C14908, C07C14800

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040026868

ABSTRACT:
Primary aliphatic (preferably alkyl) mercaptans are prepared by heating a phosphorus-sulfur compound, preferably a primary aliphatic phosphorodithioic acid, with a basic nitrogen compound. The preferred basic nitrogen compounds are amines and particularly aliphatic primary and secondary amines, especially alkylene polyamines.

REFERENCES:
W. Theilheimer; Syn. Method of Org. Chem., vol. 17, pp. 46-47.

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