Method of preparing para-chlorotoluene

Chemistry: electrical and wave energy – Processes and products

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204294, C25B 306

Patent

active

042696747

ABSTRACT:
A method of preparing para-chlorotoluene by the electrolytic chlorination of toluene in an aqueous solution of hydrogen chloride or a metal halide as an electrolyte by passing an electric current from a cathode to an anode, both of which are immersed in the electrolyte, in order to form an active chlorine species which then reacts with toluene to produce the desired para-toluene. The anode is made of a carbonaceous material having cyclodextrin or a derivative thereof bonded onto its surface. The toluene that is introduced into the aqueous solution of electrolyte is included as a clathrate compound within the cyclodextrin.

REFERENCES:
patent: 3692646 (1972-09-01), Mather et al.

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