Method of preparing metallocene compounds

Chemistry of hydrocarbon compounds – Compound or reaction product mixture – Aromatic

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528395, 556138, C07C 1512

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active

048515981

ABSTRACT:
This invention describes a novel method of preparing metallocene compounds. The invention is based on synthesis of novel bis cyclopentadienides that, under appropriate conditions, will either encapsulate a transition metal to produce a metallocene such as ferrocene, or ferrocene derivative, or will yield a polymeric metallocene. Compounds produced by this process are useful as catalyst in propulsion systems, or as anti-knock compounds in gasolines.

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Katz, T. J. and J. Pesti, J. Am. Chem. Soc., 104:346-347, 1982.
Neuse, E. W. and L. Bednarik, Transition Metal Chemistry, 4:87-94, 1979.
Felkin, H. and G. Swierczewski, Tetrahedron, 31:2735-2748, 1975.
Sudhakar, A., T. J. Katz and B.-W. Yang, J. Am. Chem. Soc., 108:2790, 1986.

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