Method of preparing cross-linked polydiorganosiloxane using orga

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

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521170, 528 11, 528 21, 528 28, 528 30, 528 33, C08J 900

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042346975

ABSTRACT:
A crosslinked polydiorganosiloxane is prepared by mixing a mercapto-functional polydiorganosiloxane endblocked with organosiloxy units of formulae ##STR1## an organic diisocyanate, a catalyst, such as a tertiary organic amine and water. The resulting product is a sponge if the water is added in the liquid state or a non-porous elastomer if the water in the gas state is allowed to penetrate a blend of the polydiorganosiloxane, organic diisocyanate and tertiary organic amine. Density of sponge prepared by this method can range from about 35 kilograms per cubic meter to about 750 kilograms per cubic meter. A blend of the mercapto-functional polydiorganosiloxane, organic diisocyanate and tertiary organic amine can be used to make sponge by adding water in the liquid state or a non-porous elastomer by exposing it to air.

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