Method of preparing active magnesium-hydride or magnesium hydrog

Details Method of preparing active magnesium-hydride or magnesium hydrog Method of preparing active magnesium-hydride or magnesium hydrog

1983-06-01

1985-11-19

Carter, H. T.

Chemistry of inorganic compounds

Hydrogen or compound thereof

Binary compound

423644, 420900, C01B 604

Patent

active

045541523

ABSTRACT:
A method of preparing an active magnesium-hydride or magnesium hydrogen-storer system which can reversibly take up H.sub.2, comprising contacting finely divided magnesium hydride or metallic magnesium with a solution of a metal complex or of a metal-organic compound of a transition metal of Subgroups IV-VIII of the periodic table, and then removing the solution. The product performs better with regard to speed and efficiency upon repeated hydrogenation and dehydrogenation, as in hydrogen storage and evolution.

REFERENCES:
patent: 3030184 (1962-04-01), Faust et al.
patent: 3485585 (1969-12-01), Snyder
patent: 3617218 (1971-11-01), Tamelen et al.
patent: 4200623 (1980-04-01), Muller et al.
patent: 4200624 (1980-04-01), Muller et al.
patent: 4389326 (1983-06-01), Tanguy et al.
Ashby et al., "J. of American Chem. Soc.", vol. 99, 1977, pp. 310-311.

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