Method of preparing a hydrocarbylated metal-organic compound

Details Method of preparing a hydrocarbylated metal-organic compound Method of preparing a hydrocarbylated metal-organic compound

2004-08-03

2010-10-19

Gonzalez, Porfirio Nazario (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

C556S019000, C548S101000, C534S015000

Reexamination Certificate

active

07816548

ABSTRACT:
The invention relates to a process for the preparation of a hydrocarbylated metal organic compound, comprising a hydrocarbyl group, a spectator ligand and optionally a ligand, by contacting a metal-organic reagent with a spectator ligand in the presence of at least 2 equivalents of a hydrocarbylating agent. The invention further relates to a hydrocarbylated metal organic compound according to the following formulacontaining a spectator ligand S equal to (Ar—Z—)sY(—Z-DR′n)q, wherein Y represents the an anionic moiety of S bonded to M of the metal-organic compound, Z an optional bridging group between the Y moiety and the DR′nand/or Ar group, D an electron donating hetero atom chosen from group 15 or 16, R′ an optional substituent, Ar an electron-donating aryl group, n the number of R′ groups bonded to D, q and s integers with q+s≧1, wherein Y is an imine radical, or wherein the electron donating hetero atom containing group DR′—nis a ketimide, phosphinimide, guanidine, or iminoimidazoline, or a combination thereof.

REFERENCES:
patent: 2243726 (2000-01-01), None
patent: WO 96/13529 (1996-05-01), None
patent: WO 02/070569 (2002-09-01), None
Zhang et al., J. Am. Chem. Soc., vol. 122, No. 23, pp. 5499-5509 (2000).
Stephan et al., Organometallics, vol. 18, No. 7, pp. 1116-1118 (1999).
International Search Report, (2004).
Ulrich Siemeling et al; “Synthesis and Structure of [Nbcl3{[NPPh2(C5H4)]2Fe}]: The First Structurally Characterised Complex Containing a chelating Di(phosphaneiminato) Ligand”; Z. Anorg. Allg. Chem. 2000 ; vol. 626, No. 4, pp. 825-826.
Matthew G. Thorn et al; “Synthesis and Chemistry of Titanacyclopentane and Titanacyclopropane Rings Supported by Aryloxie Ligation”; 1997 American Chemical Society; vol. 119, pp. 8630-8641.
John E. Hill et al; “Formation, Fragmentation, and Isomerization of Azatitanacycle Rings Supported by Aryloxide Ligation”; Organometallics 1992; vol. 11, pp. 1775-1777; 1992 American Chemical Soceity.
Kattesh V. Katti et al; “Synthesis and Characterization of New Heterocyclic Compounds of Tungsten, Selenium, and Tellurium”; Inorg. Chem. 1987; vol. 26, pp. 814-816.
Herbert W. Roesky et al; “Wolframheterocyclen mit Phosphor, Schwefel und Stickstoff als Ringbausteine”; Chem. Ber. vol. 122, No. 1, (1989); pp. 63-65.
Herbert W. Roesky et al; “Darstellung eines cyclischen Ferrocenderivates mit Wolfram(VI)”; Organische Chemie; vol. 43, No. 2, 1988, pp. 231-232.

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