Method of preparation of (substituted-thio)alkyl isothiocyanates

Details Method of preparation of (substituted-thio)alkyl isothiocyanates Method of preparation of (substituted-thio)alkyl isothiocyanates

1987-08-26

1988-10-25

Rotman, Alan L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Isothiocyanate esters

C07C119042

Patent

active

047805579

ABSTRACT:
A one-step process for the preparation of (substituted-thio)alkyl isothiocyanates in high yield comprising contacting a haloalkyl sulfide with a thiocyanate salt in the absence of a catalyst under reaction conditions sufficient to produce the desired (substituted-thio)alkyl isothiocyanate is disclosed. Examples of compounds produced by this process include CH.sub.3 SCH.sub.2 CH.sub.2 NCS and n-C.sub.6 H.sub.13 SCH.sub.2 CH.sub.2 NCS.
The compounds produced by this process are useful as intermediates in the synthesis or ore flotation chemicals such as substituted thiocarbamates or thioureas.

REFERENCES:
patent: 3160649 (1964-12-01), Hasselstrom et al.
patent: 3584028 (1971-06-01), Argabright et al.
patent: 4479903 (1984-10-01), Dauplaise
Acta Chemica Scandinavica II, Anders Kjaer, Bo Christensen, 1298-1307.
Organic Chemistry of Bivalent Sulfur, VI, 64, E. E. Reid (ed, Chemical Publishing Co., Inc. (1965)).
Uch. Zap. Azerb. Bos. Univ., Ser. Khim. Nauk. (#1), 50-51 (1972).
J5 8090-546-A, Kinjirushi Wasabik.
J5 7134-461, Nihon Noyaku KK.

Affiliated with

Also associated with

Rating

Method of preparation of (substituted-thio)alkyl isothiocyanates does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Method of preparation of (substituted-thio)alkyl isothiocyanates, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method of preparation of (substituted-thio)alkyl isothiocyanates will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2270373