Method of performing hydrous pyrolysis for studying the kinetic

Chemistry: analytical and immunological testing – Geochemical – geological – or geothermal exploration – For petroleum oils or carbonaceous minerals

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436 32, 436 34, 436157, 436177, G01N 2514

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050827871

ABSTRACT:
A method for studying the rate and type of hydrocarbon generated from a hydrocarbon source utilizes hydrous pyrolysis to generate hydrocarbons from the sample and then utilizes cryogenic methods to remove the fluid portions to a transfer vessel. The gaseous components are removed to a further vessel of known dimensions for determination of weight. The hydrocarbons in the transfer vessel are passed through a dryer to separate the water and their makeup determined. The hydrocarbons remaining in the reactor vessel are removed by working with solvents and their weights are determined after separation and evaporation of the solvents.

REFERENCES:
Winters et al., "A Laboratory Study of Petroleum Generation by Hydrouspyrolysis", Advances in Organic Geochemistry, 1981, M. Bjoroy ed. New York: Wiley, 1983, pp. 524-532.
Monthioux, M. et al., "Comparison Between Natural and Artificial Maturation Series of Humic Coals from the Mahakam Delta, Indonesia", Org. Geochem., vol. 8, No. 4, pp. 275-292, 1985.
Burnham, A. K. et al., "Comparison of Methods for Measuring Kerogen Pyrolysis Rates and Fitting Kinetic Parameters", 193rd Meeting of the American Chemical Society, Denver, Colo., Apr. 5, 1987.

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