Method of operating chlor-alkali cells

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Treating electrode – diaphram – or membrane during synthesis

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205516, C25B 1500, C25B 134

Patent

active

055672981

ABSTRACT:
Disclosed is an improved method of making chlorine and alkali metal hydroxide, e.g., sodium hydroxide, in an electrolytic cell of the type wherein a liquid permeable diaphragm separates the anolyte from the catholyte, said method comprising adding to the anolyte, while the cell is operating, a hydrated aluminum silicate containing clay mineral, followed by lowering the pH of the anolyte by the addition of an inorganic acid and maintaining the anolyte at said lowered pH for a time sufficient to restore the cell to a predetermined current efficiency.

REFERENCES:
patent: 3755103 (1973-08-01), Grotheer et al.
patent: 4036729 (1977-07-01), Patil et al.
patent: 4169774 (1979-10-01), Kadija et al.

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