Method of oligomerizing 1-olefins and regenerating a heterogeneo

Details Method of oligomerizing 1-olefins and regenerating a heterogeneo Method of oligomerizing 1-olefins and regenerating a heterogeneo

1982-08-04

1984-01-31

Konopka, P. E.

Chemistry of hydrocarbon compounds

Unsaturated compound synthesis

By addition of entire unsaturated molecules, e.g.,...

502 36, 526237, 585510, C07C 202, B01J 2732

Patent

active

044291779

ABSTRACT:
An alpha-olefin is oligomerized in the presence of a three-component catalyst comprising a particulate solid adsorbent, boron trifluoride and elemental oxygen. The process also activates the catalyst. For example, 1-decene is oligomerized to a product predominating in the trimer and tetramer using boron trifluoride, elemental oxygen and silica as the solid adsorbent.

REFERENCES:
patent: 2404788 (1946-07-01), Burk et al.
patent: 2418797 (1947-04-01), Voorhees
patent: 2568209 (1951-09-01), Wackher et al.
patent: 4213001 (1980-07-01), Madgavker et al.
patent: 4263467 (1981-04-01), Madgavkar
patent: 4365105 (1982-12-01), Morganson et al.

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