Method of measuring metallic cation and water transport numbers

Chemistry: electrical and wave energy – Processes and products

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204261, 204415, G01N 2728, G01N 2740

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active

043790291

ABSTRACT:
An electrolytic membrane transport cell adaptable to experimental use for the purpose of accurately measuring simultaneously cation transport and water transport numbers (mol/Faraday) under operating conditions similar to those used in commercial chlor-alkali membrane cells. The cell comprises a pair of half cells each containing a truncated conical chamber adapted to matingly fit together, when abutted at their apexes, and to form a cell, said cell being adapted to hold a permselective membrane which is sealingly supported between said half cells so as to create separate anode and cathode sections, electrode means, heating means, stirring means and electrolyte inlet means. When used in conjunction with radioactive tracer techniques considerable improvements in the accuracy and ease with which transport phenomena can be studied are possible.

REFERENCES:
patent: 4090924 (1978-05-01), Bon
M. Maksimishin et al., Industrial Laboratory, (Trans. of: Zavod. Lab., (USSR), vol. 39, No. 10, pp. 1674-1675, Oct. 1973.

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