Method of manufacturing semiconductor devices

Etching a substrate: processes – Forming or treating material useful in a capacitor

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Details

216 76, 438717, 438722, 438736, 438738, H01L 21302

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active

058402004

ABSTRACT:
A device insulating film, a lower-layer platinum film, a ferroelectric film, an upper-layer platinum film, and a titanium film are sequentially formed on a semiconductor substrate in this order. On the titanium film, a photoresist mask is further formed in a desired pattern. The thickness of the titanium film is adjusted to be 1/10 or more of the total thickness of a multilayer film consisting of the upper-layer platinum film, the ferroelectric film, and the lower-layer platinum film. The titanium film is then subjected to dry etching and the photoresist film is removed by ashing process. The titanium film thus patterned is used as a mask in etching the upper-layer platinum film, the ferroelectric film, and the lower-layer platinum film by a dry-etching method using a plasma of a gas mixture of chlorine and oxygen in which the volume concentration of oxygen gas is adjusted to be 40%. During the dry-etching process, the titanium film is oxidized to provide a high etching selectivity. Subsequently, the titanium film is removed by dry etching using a plasma of chlorine gas.

REFERENCES:
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patent: 5443688 (1995-08-01), Toure et al.
"A Gbit-Scale Dram Stocked Capacitor with ECR MOCVD Sr Ti O.sub.3 Over RIE Patterned RuO.sub.2/ Tin Storage Nodes"; Integrated Ferroelectrics; 1995; vol. II, pp. 81-100; Lesaicherre et. al.
"Reactive Ion Etching of Ru O.sub.2 Thin Films Using The Gas Mixture O.sub.2 --CF.sub.3 CFH.sub.2 "; Wei et. al; J. Vac. Sci. Tech B, vol. 12, No. 6, pp. 3208-3213, Dec. 1994.
"Reactive Ion Etching of Lead Zirconate Titanate (PZT) Thin Film Capacitors"; Vijay et. al.; J. Elect. Soc., vol. 140, No. 9, Sep. 1993.
Yokoyama et al., "High-Temperature Etching of PZT/Pt/TiN Structure by High Density ECR Plasma", International Conference on Solid State Devices and Materials, pp. 721-723 (Aug. 23, 1994).
Charlet et al., "Dry Etching of PZT Films in an ECR Plasma", Proceedings of the International Colloquium on Plasma Processes, pp. 334-339 (Jun. 6-11, 1993).

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