Method of manufacturing semiconductor device with reduced...

Semiconductor device manufacturing: process – Making passive device – Stacked capacitor

Reexamination Certificate

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C438S393000, C438S394000, C438S395000, C438S250000, C438S251000, C438S252000, C438S253000, C438S386000, C257S532000, C257S528000, C257S306000, C257S379000

Reexamination Certificate

active

06762109

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method of manufacturing a semiconductor device and a method of forming a capacitor.
2. Description of the Background Art
FIGS. 57
to
61
are cross sectional views showing a sequence of process steps in a first conventional semiconductor device manufacturing method. First, referring to
FIG. 57
, an element isolation insulating film
201
is partially formed in the upper surface of a silicon substrate
200
. Then, referring to
FIG. 58
, a polysilicon film
202
serving as a lower electrode of a capacitor is partially formed on the element isolation insulating film
201
. Then, referring to
FIG. 59
, an insulation film
203
serving as a capacitor dielectric film is formed on the element isolation insulating film
201
to cover the polysilicon film
202
. The insulation film
203
is, for example, an ON film formed by stacking silicon oxide film and silicon nitride film one above the other.
Referring next to
FIG. 60
, a silicon oxide film
204
is formed by thermal oxidation on an upper surface portion of the silicon substrate
200
where the element isolation insulating film
201
is not formed. After formation of a polysilicon film on the whole surface, the polysilicon film is patterned to form a gate electrode
205
and a polysilicon film
206
serving as an upper electrode of the capacitor. The polysilicon film
206
is opposed to the polysilicon film
202
with the insulation film
203
sandwiched in between. Then, referring to
FIG. 61
, source/drain regions
207
are formed in the upper surface of the silicon substrate
200
by ion implantation of impurities. At this time, impurities are also implanted into the gate electrode
205
and the polysilicon film
206
.
FIGS. 62
to
67
are cross sectional views showing a sequence of process steps in a second conventional semiconductor device manufacturing method. First, referring to
FIG. 62
, a copper film
301
serving as a lower electrode of a capacitor is partially formed in the upper surface of an interlayer insulation film
300
. Then, a capping film
302
of silicon nitride film is formed on the whole surface. In general, the capping film is formed to prevent copper atoms contained in a copper wire from diffusing into the interlayer insulation film. Then, referring to
FIG. 63
, a silicon oxide film
303
is formed on the capping film
302
.
Referring next to
FIG. 64
, a photoresist
304
having a predetermined opening pattern is formed on the silicon oxide film
303
. Using the photoresist
304
as an etch mask, the silicon oxide film
303
and the capping film
302
are etched to form a trench
305
. Then, referring to
FIG. 65
, after removal of the photoresist
304
, an insulation film
306
such as an ON film is formed on the whole surface.
Referring next to
FIG. 66
, by filling in the trench
305
, a copper film
307
is formed on the whole surface. Then, referring to
FIG. 67
, the copper film
307
and the insulation film
306
are polished by CMP (Chemical Mechanical Polishing) until the upper surface of the silicon oxide film
303
is exposed. This forms an insulation film
308
serving as a capacitor dielectric film and a copper film
309
serving as an upper electrode of the capacitor in the trench
305
. Through the above process steps, an MIM (Metal Insulator Metal) type capacitor is formed by a damascene process.
According to the first conventional semiconductor device manufacturing method, impurities are introduced by ion implantation into the polysilicon film
206
serving as the upper electrode of the capacitor. Thus, the impurity concentration of the polysilicon film
206
in the bottom part is lower than that in the upper part. That is, the polysilicon film
206
has a low impurity concentration in a portion where it is in contact with the insulation film
203
serving as a capacitor dielectric film. This causes depletion of the polysilicon film
206
at the interface with the insulation film
203
, thereby causing a problem of capacitor performance degradation such as variations in capacitance due to changes in the applied voltage or temperature.
According to the second conventional semiconductor device manufacturing method, on the other hand, since the upper electrode of the capacitor is formed of the copper film
309
, the above problem of the first manufacturing method does not arise. This method, however, requires additional independent process steps for capacitor formation (
FIGS. 63
to
67
), aside from the process steps for interconnection formation, which causes a problem of increasing the total number of manufacturing process steps.
SUMMARY OF THE INVENTION
An object of the present invention is to provide a method of manufacturing a semiconductor device and a method of forming a capacitor which allow the formation of a high-performance capacitor without increasing the number of process steps.
According to an aspect of the present invention, the method of manufacturing a semiconductor device includes the following steps (a) to (g). The step (a) is to prepare a substrate. The step (b) is to partially form an element isolation insulating film in a main surface of the substrate. The step (c) is to form a first semiconductor element in a first element forming region defined by the element isolation insulating film, the first semiconductor element having first source/drain regions formed in the main surface. The step (d) is to form a first electrode of a capacitor. The step (e) is to form a silicide protection film of insulation film to cover the first electrode, but not to cover the first semiconductor element. The step (f) is to form a first silicide layer by silicidation of the first source/drain regions. The step (g) is to form a second electrode of the capacitor which is opposed to the first electrode with the silicide protection film sandwiched in between.
The silicide protection film serves as a capacitor dielectric film. Thus, the number of process steps can be reduced when compared with that in the case where a capacitor dielectric film is formed aside from a silicide protection film.
According to another aspect of the present invention, the method of manufacturing a semiconductor device includes the following steps (a) to (f). The step (a) is to prepare a substrate. The step (b) is to partially form an element isolation insulating film in a main surface of the substrate. The step (c) is to form a semiconductor element in a first element forming region defined by the element isolation insulating film, the semiconductor element having source/drain regions formed in the main surface. The step (d) is to form a first electrode of a capacitor. The step (e) is to form an etching stopper film of insulation film to cover the semiconductor element and the first electrode. The step (f) is to form a second electrode of the capacitor which is opposed to the first electrode with the etching stopper film sandwiched in between.
The etching stopper film serves as a capacitor dielectric film. Thus, the number of process steps can be reduced when compared with that in the case where a capacitor dielectric film is formed aside from an etching stopper film.
According to still another aspect of the present invention, the method of manufacturing a semiconductor device includes the following steps (a) to (c). The step (a) is to form a first metal film serving as a first interconnection and a second metal film serving as a first electrode of a capacitor, within a first interconnection layer. The step (b) is to form a capping film to cover the first and second metal films. The step (c) is to form a third metal film serving as a second electrode of the capacitor within a second interconnection layer formed on the first interconnection layer, the third metal film being opposed to the second metal film with the capping film sandwiched in between.
The capping film serves as a capacitor dielectric film. Thus, the number of process steps can be reduced when compared with that in the case where a capacitor dielectric film

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