Method of manufacturing a composite material having a pyrolytic

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Rod – strand – filament or fiber

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428368, 428375, 428378, 428388, 428698, 428902, 428903, 4272481, 427249, 427255, 4272552, 4274192, 4274197, C23C 1600, C23C 1626, B32B 900

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055522203

ABSTRACT:
The pyrolytic carbon lamellar interphase is formed on the reinforcing fibers inside a chamber in which a plurality of successive cycles is performed, each cycle comprising: injecting a reaction gas in which the pyrolytic carbon precursor is selected from alkanes, excluding methane taken as a sole component, alkenes, alkynes, and aromatic hydrocarbons, and mixtures thereof; the gas is maintained inside the chamber for a first predetermined time period to form an interphase layer of controlled thickness of nanometer size; the gaseous reaction products are then evacuated during a second time period; the cycles being performed consecutively in the chamber until the thickness desired for the interphase has been obtained, thereby achieving a lamellar interphase that is highly anisotropic, whose lattice fringe texture has distorted fringes of total length (L.sub.2) not less than 4 nanometers on average with maximum values exceeding 10 nanometers.

REFERENCES:
patent: 4752503 (1988-06-01), Thebault
patent: 4823734 (1989-04-01), Christin
patent: 5026604 (1991-06-01), Thebault
"Pulse CVI of Porous Carbon", Kohzo Sugiyama, et al, Journal of Materials Science Letters 6 (1987), pp. 331-333.
"Reinforcement and Antioxidizing of Porous Carbon by Pulse CVI of SiC", Kohzo Sugiyama, et al, Journal of Materials Science 24 (1989) pp. 3756-3762.
"Quantitative Analysis of Carbon Coating Anisotropy for CMC Interfaces", X. Bourrat, et al., LCTS, Laboratoire des Composites Thermostructuraux, UMR 47:CNRS-SEP-UB, pp. 94-95.
"Electrically Conductive Grades of Carbon Black: Structure and Properties", Xavier Bourrat, Carbon vol. 31, No. 2. pp. 287-302, 1993.
"High Resolution TEM Studies of Carbonization and Graphitization", Anges Oberlin, Laboratoire Marcel Mathieu, CNRS-Universite, Pau, France. pp. 1-143.

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