Method of manufacturing 1-indanone

Details Method of manufacturing 1-indanone Method of manufacturing 1-indanone

1999-07-01

2000-10-03

Padmanabhan, Sreeni

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568322, 568330, 568661, C07C 4530, C07C 4302

Patent

active

061275794

ABSTRACT:
A method of manufacturing the useful substance 1-indanone from easily obtainable materials consists of reacting an indanyl ether represented by the generic formula ##STR1## under basic conditions to give a novel substance which is the indenyl ether derivative represented by the generic formula ##STR2## and hydrolyzing this to give the 1-indanone represented by the generic formula ##STR3##

REFERENCES:
patent: 5841000 (1998-11-01), Igarashi et al.
"Efficient Intramolecular General Acid Catalysis of Enol Ether Hydrolysis, Hydrogen-bonding Stabilisation of the Transition State for Proton Transfer to Carbon", J. Chem. Soc., Perkin Trans 2, 1994, by Anthony J. Kirby et al.
"Chromium(II)--catalyzed Electrochemical Dehalogenation of .beta.-Hydroxyhalides--Convenient Entry to Deoxynucleosides", Agnew. Chem. Int. Ed. 1980; vol. 19(1), pp. 46-47, by Wellman et al.
"Tautomerism of the Monohydroxy Derivatives of Five-Membered O, N, S Heterocycles", J. Am. Chem. Soc. 1989; vol. 111, pp. 5346-5356, by Brian Capon et al.
"Some Bromine Derivatives of Indene and Indane", Journal of the American Society, vol. 57, 1935, pp. 2022-2026, by H.D. Porter et al.

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