Metal treatment – Process of modifying or maintaining internal physical... – Magnetic materials
Patent
1988-04-26
1990-02-20
Sheehan, John P.
Metal treatment
Process of modifying or maintaining internal physical...
Magnetic materials
148102, 148103, 148104, 419 12, 419 13, 419 19, 419 20, 419 28, 419 29, 419 55, 419 57, H01F 102
Patent
active
049023578
DESCRIPTION:
BRIEF SUMMARY
This invention concerns a heat treatment method for rare earth type permanent magnets, principally those of the Nd-Fe-B variety.
BACKGROUND OF THE TECHNOLOGY
Since the discovery that there would be theoretically very high magnetic properties [(BH) max.about.50 MGOe] when rare earth metals and transition metals are combined into metal compounds in a ratio of 2:17 to form a rare earth-transition metal alloy, there have been a number of attempts to obtain practical permanent magnet applications using these types of compounds. One example is the Sm-Co-Cu-Fe metal compound where (BH)max has reached .about.30 MGOe. Further, with Nd-Fe metal compounds, high magnetic properties of (BH)max.about.40 MGOe have been reached. These alloy formulations are crushed into powder, and then aligned and compression formed in a magnetic field, or formed in a non-magnetic field, sintered, solution-treated, and aged to form a mass, and then cut and polished into permanent magnets of the shape required according to the most usual methods of their preparation. Since the rare earth and ferrous type permanent magnets, particularly the R-Fe-M permanent magnets (where R represents one or more types of rare earth metals, and M represents B or other metalloid element), are easily oxidized when exposed to air, when they are used in precision applications, such as in miniature electronic parts for magnetic circuits using permanent magnets, there are many instances were oxidation caused by exposure of the magnet to air leads to a degradation of the magnetic properties and fluctuations in their permanence due to changes in the magnetic space. Because of this, the prior art has used Cr or Ni plating to cover the surface to prevent this oxidation.
When wet type plating means are used, however, the surface of the permanent magnet itself can be corroded by the degreasing and oxidation removal processes, which makes plating difficult. In addition, following the plating operation, gaps sometimes exist between the permanent magnet surface and the plating. Peeling of the plating is likely in these areas. Also, pinhole defects are common. Overall magnetic properties are additionally likely to be affected by the numerous processing steps involved, sintering, solution treating, aging, machining (cutting grinding and polishing) to obtain the desired magnetic properties and shape, etc., which are apt to lead to surface defects. FIG. 1A shows a graph of the resulting demagnetization curve where the effects above types of defects can be seen. These phenomena are especially dramatic in permanent magnets which have a relatively small volume but a relatively large surface area. Such defects result in lower producton yields.
DISCLOSURE OF THE INVENTION
This invention concerns a permanent magnet alloy conforming to the general formula: R(T, M)z (where R represents one or a mixture of two or more rare earth metals, T is transition metals such as Fe or Co, M is a metalloid element such as B, and z is 4 to 9) where the alloy is crushed and compressed in a magnetic or, a non-magnetic field to form the green body. Then first, for permanent magnets having a small surface area/volume ratio, they are sintered at a temperature of 900.degree. to 1200.degree. C., then machined into appropriate shapes, and then solution treated at 900.degree. to 1200.degree. C. in a 10.sup.-8 to 1 Torr gas atmosphere, after which they are aged at 300.degree. to 900.degree. C. Secondly, for permanent magnets having a large surface area volume ratio, they are sintered at 900.degree. to 1200.degree. C., solution treated at 900.degree. to 1200.degree. C., machined into appropriate shapes, and then aged in a gas atmosphere of 10.sup.-8 Torr at 300.degree. to 900.degree. C. Thirdly, they can be sintered at 1000.degree. to 1200.degree. C., machined into usable shapes, re-sintered in a 10.sup.-8 to 1 Torr gas atmosphere at 1000.degree. to 1200.degree. C., in order to manufacture these permanent magnets. The gas environment used for these various processes may be oxygen, nitrogen or a mixture
REFERENCES:
patent: 4597938 (1986-07-01), Matsuura et al.
patent: 4601875 (1986-07-01), Yamamoto et al.
Namiki Precision Jewel Co. Ltd.
Sheehan John P.
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