Method of manufacture of molecular sieves

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – Activating treatment

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502 64, 502 60, 502 73, 502 79, 502 78, 502 80, 502 84, C01B 3902

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059168366

ABSTRACT:
Zeolites exchanged with lithium ions and, optionally, with polyvalent cations are prepared by ion-exchanging a sodium-containing zeolite, a potassium-containing zeolite or a sodium- and potassium-containing zeolite with ammonium ions, thereby replacing the sodium and/or potassium ions with ammonium ions, and then reacting the ammonium ion-exchanged zeolite with a water-soluble lithium compound under conditions which result in the removal of ammonia from the reaction zone. Polyvalent ions, which may be present in the zeolite undergoing ion-exchange, will not be substantially replaced by the ammonium or lithium ions.

REFERENCES:
patent: 3405055 (1968-10-01), Bittner
patent: 3576901 (1971-04-01), Kokotailo et al.
patent: 3732326 (1973-05-01), Chen
patent: 3794598 (1974-02-01), Schlaffer
patent: 3985859 (1976-10-01), Blaine
patent: 4724275 (1988-02-01), Hinnenkamp et al.
patent: 5268023 (1993-12-01), Kirner
patent: 5464467 (1995-11-01), Fitch et al.

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