Method of making thermal insulating device by winding

Details Method of making thermal insulating device by winding Method of making thermal insulating device by winding

2002-03-22

2004-08-03

Aftergut, Jeff H. (Department: 1733)

Adhesive bonding and miscellaneous chemical manufacture

Methods

Surface bonding and/or assembly therefor

C156S155000, C156S191000, C156S307300, C156S307700

Reexamination Certificate

active

06770161

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to a thermal insulating device. More particularly, the present invention relates to a thermal insulating device useful for a high temperature reactor, such as a reactor that utilizes highly reactive chemical gases, such as inorganic halides, especially chlorine and fluorine, in a non-oxidizing atmosphere. The inventive thermal insulating device includes a shell comprising resin bonded spiral wound continuous flexible graphite sheet.
BACKGROUND OF THE INVENTION
Graphites are made up of layer planes of hexagonal arrays or networks of carbon atoms. These layer planes of hexagonally arranged carbon atoms are substantially flat and are oriented or ordered so as to be substantially parallel and equidistant to one another. The substantially flat, parallel equidistant sheets or layers of carbon atoms, usually referred to as basal planes, are linked or bonded together and groups thereof are arranged in crystallites. Highly ordered graphites consist of crystallites of considerable size: the crystallites being highly aligned or oriented with respect to each other and having well ordered carbon layers. In other words, highly ordered graphites have a high degree of preferred crystallite orientation.
Graphites possess anisotropic structures and thus exhibit or possess many properties that are highly oriented, i.e. directional. Graphites may be characterized as laminated structures of carbon, that is, structures consisting of superposed layers or laminae of carbon atoms joined together by weak van der Waals forces. In considering the graphite structure, two axes or directions are usually noted, i.e. the “c” axis or direction and the “a” axes or directions. For simplicity, the “c” axis or direction may be considered as the direction perpendicular to the carbon layers. The “a” axes or directions may be considered as the directions parallel to the carbon layers or the directions perpendicular to the “c” direction. Natural graphites possess a high degree of orientation and hence anisotropy with respect to thermal and electrical conductivity and other properties.
As noted above, the bonding forces holding the parallel layers of carbon atoms together are only weak van der Waals forces. Graphites can be treated so that the spacing between the superposed carbon layers or laminae can be appreciably opened up so as to provide a marked expansion in the direction perpendicular to the layers, that is, in the “c” direction and thus form an expanded or intumesced graphite structure in which the laminar character is substantially retained.
Graphite flake which has been greatly expanded and more particularly expanded so as to have a final thickness or “c” direction dimension which is up to about 80 or more times the original “c” direction dimension can be formed without the use of a binder into cohesive or integrated sheets, e.g. webs, papers, strips, tapes, or the like. The formation of graphite particles which have been expanded to have a final thickness or “c” dimension which is up to about 80 or more times the original “c” direction dimension into integrated sheets without the use of any binding material is believed to be possible due to the excellent mechanical interlocking, or cohesion which is achieved between the voluminously expanded graphite particles.
In addition to flexibility, the sheet material, as noted above, has also been found to possess a high degree of thermal anisotropy. Sheet material can be produced which has excellent flexibility, good strength and is highly resistant to chemical attack and has a high degree of orientation.
Briefly, the process of producing flexible, binderless graphite sheet material comprises compressing or compacting under a predetermined load and in the absence of a binder, expanded graphite particles which have a “c” direction dimension which is up to about 80 or more times that of the original particles so as to form a substantially flat, flexible, integrated graphite sheet. Once compressed, the expanded graphite particles, which generally are worm-like or vermiform in appearance, will maintain the compression set. The density and thickness of the sheet material can be varied by controlling the degree of compression. The density of the sheet material can be within the range of from about 0.08 g/cm
3
to about 2.0 g/cm
3
. The flexible graphite sheet material exhibits an appreciable degree of anisotropy, with the degree of anisotropy increasing upon roll pressing of the sheet material to increased density. In roll pressed anisotropic sheet material, the thickness, i.e. the direction perpendicular to the sheet surface comprises the “c” direction and the directions ranging along the length and width, i.e. along or parallel to the surfaces comprises the “a” directions.
SUMMARY OF THE INVENTION
The present invention comprises a shell, preferably a self-supporting, cylindrically shaped shell, having two ends (denoted for the sake of convenience as “top” and “bottom” useful, for instance, for surrounding a high temperature radiant heat source, such as a reactor in which highly chemically active gases are contained. The shell can be used as a heat shield to reflect radiant heat energy back to the reactor and to minimize loss of thermal energy due to conduction. The aforementioned shell comprises multiple layers formed from a continuous spiral wound sheet of anisotropic flexible graphite, bonded with a cured resin. The resin is coated on both sides of a thin sheet of heat decomposable carbon based material that during the fabrication process is co-extensive with the spiral wound sheet of flexible graphite and is cured in situ. The thin sheet of heat decomposable carbon based material provides a path for the escape of gases which develop in the course of in situ curing of the resin; this path, resulting from the aforesaid decomposition, is provided between the layers of the sheet of carbon-based material and spiral wound flexible graphite and further enables contact between resin applied on both, i.e. the opposite, sides of the sheet of heat decomposable carbon-based material in the course of in situ curing of the resin. This results in a strong continuous bonding layer of resin between, and co-extensive with, the spiral wound sheet of flexible graphite.
In a further embodiment of the present invention, a second shell essentially identical to the first shell, except for being larger in cross-section, is provided. The second shell is positioned to surround the first shell so as to define an annular chamber therebetween, the annular chamber also having two ends (also conveniently denoted “top” and “bottom”) therebetween. Uncompressed particles of expanded graphite can be provided in the annular chamber as an insulating material, preferably so as to essentially fill the annular chamber. Other insulating materials that can be employed include carbon felt, graphite felt, rigid insulation, ceramic wool fibers, and even gases like argon or air. Indeed, insulation can also be provided by drawing a vacuum in the annular chamber.
The annular chamber can be closed, at one or both of its ends, by one or more flexible sheets of graphite that are advantageously resin-bonded to one or both of the first and second shells. Preferably, the covering flexible sheets of graphite are themselves multi-layered, with the individual layers bonded to resin, in the same manner as the shell is formed. As was the case with the inventive shell, the resin is coated on both sides of a thin sheet of heat decomposable carbon based material that during the fabrication process is co-extensive with the sheet of flexible graphite and is cured in situ. The thin sheet of heat decomposable carbon based material provides a path for the escape of gases which develop in the course of in situ curing of the resin; this path, resulting from the aforesaid decomposition, is provided between the layers of the flexible graphite and further enables contact between resin applied on both, i.e. the opposite, sides of the sheet of heat decomposable carbon-based material in t

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