Method of making self-promoted hydrotreating catalysts

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Sulfur or compound containing same

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502162, 502220, 208421, 208112, 208143, 208217, 208216R, 208254H, 518713, 518714, 518715, 208422, B01J 27047, B01J 3100, B01J 27051, C10G 106

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045956723

ABSTRACT:
Self-promoted molybdenum and tungsten sulfide hydrotreating catalysts are prepared by heating one or more water soluble catalyst precursors in a non-oxidizing atmosphere in the presence of sulfur at a temperature of at least about 200.degree. C. The precursors will be one or more compounds of the formula ML(Mo.sub.y W.sub.1-y O.sub.4) wherein M is one or more promoter metals selected from the group consisting essentially of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein O.ltoreq.y.ltoreq.1 and wherein L is a nitrogen containing, neutral multidentate, chelating ligand. In a preferred embodiment the ligand L will comprise one or more chelating alkyl di or triamines and the non-oxidizing atmosphere will comprise H.sub.2 S.

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patent: 4243554 (1981-01-01), Naumann et al.

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