Method of making rubber-modified rigid silicone resins and compo

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525476, 525478, C08F28300

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active

058309500

ABSTRACT:
Novel rubber-modified rigid silicone resins a novel method of making the same are disclosed. The resins are the copolymerized reaction product of (A) an organosilicon composition selected from the group consisting (I) an organosilicone resin, (II) hydrolyzable precursors of (I), and an hydrolyzate of (II) and (B) an silicone rubber. In the method of the invention, the copolymerization step is carried out in an organic solvent, preferably utilizing a relatively weak condensation catalyst. Thereafter, the solution is devolatilized and the composition cured by heating.

REFERENCES:
patent: 3328481 (1967-06-01), Vincent
patent: 3607972 (1971-09-01), Kiles et al.
patent: 5034061 (1991-07-01), Maguire et al.
patent: 5470923 (1995-11-01), Krahnke et al.
"Effects Of Rubber Additions On The Fracture Toughness Of A Polyester Resin", Mandell and McGarry, Section 23-F pp. 1-4.
American Chemical Society: "Cracked Toughened Polyester Resin Formulations" McGarry and Sultan pp. 527-537.
American Chemical Society: Apr. 1968; PMSE; "Molecular Network System:A Toughened Crosslinked System"; McGarry and Subramanian pp. 95-97.

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