Method of making high tc oxide superconductor particles by adjus

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

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252518, 252527, 420901, 423263, 423593, 505735, C01F 1104, C01F 1700

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049620827

ABSTRACT:
Techniques for the preparation of superconducting perovskites in the MBa.sub.2 Cu.sub.3 O.sub.7-y system wherein M represents yttrium of a rare earth element and y is an integer ranging from 0.1 to 0.8 are described. The techniques involve the use of either a sol-gel or controlled precipitation process in which a barium solution in acetic acid is reacted with copper acetate and either a rare earth hydroxide or rare earth nitrate to form a colloid which is subsequently heated and fired to yield the desired composition. In the embodiment in which the nitrate is employed, the resultant colloid is freeze dried. In both the sol-gel and controlled precipitation processes, heating and firing are required to yield the desired characteristics.

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