Compositions – Inorganic luminescent compositions – Compositions containing halogen; e.g. – halides and oxyhalides
Reexamination Certificate
2007-08-14
2007-08-14
Koslow, C. Melissa (Department: 1755)
Compositions
Inorganic luminescent compositions
Compositions containing halogen; e.g., halides and oxyhalides
C252S30140H
Reexamination Certificate
active
10905325
ABSTRACT:
A method of making a haloapatite phosphor having a general formula represented by (Ca(1−x−y)MnxSby)5(PO4)3(F(1−z−y)ClzOy), where 0<x<0.05, 0.004<y<0.01, and 0<z<0.1. is provided. The method involves (a) formulating a blend of ingredients to make the haloapatite phosphor, the ingredients including CaHPO4as a primary source of calcium and phosphorus, (b) partially substituting an amount of an equimolar combination of an ammonium phosphate compound and calcium carbonate for an equal number of moles of CaHPO4in the formulation, (c) combining the ingredients in their formulated amounts to form the blend, and (d) firing the blend to form the haloapatite phosphor. The partial substitution has been found to increase the 100-hour brightness of the haloapatite phosphors.
REFERENCES:
patent: 4446049 (1984-05-01), Pappalardo et al.
patent: 4647399 (1987-03-01), Peters et al.
Mooney et al.,Alkaline Earth Phosphates, Chemical Reviews, vol. 61, No. 5, (1961) 433-462.
McSweeney Robert T.
Mercer Eric R.
Snyder Thomas M.
Clark Robert F.
Koslow C. Melissa
Osram Sylvania Inc.
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