Method of making haloapatite phosphors

Compositions – Inorganic luminescent compositions – Compositions containing halogen; e.g. – halides and oxyhalides

Reexamination Certificate

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C252S30140H

Reexamination Certificate

active

10905325

ABSTRACT:
A method of making a haloapatite phosphor having a general formula represented by (Ca(1−x−y)MnxSby)5(PO4)3(F(1−z−y)ClzOy), where 0<x<0.05, 0.004<y<0.01, and 0<z<0.1. is provided. The method involves (a) formulating a blend of ingredients to make the haloapatite phosphor, the ingredients including CaHPO4as a primary source of calcium and phosphorus, (b) partially substituting an amount of an equimolar combination of an ammonium phosphate compound and calcium carbonate for an equal number of moles of CaHPO4in the formulation, (c) combining the ingredients in their formulated amounts to form the blend, and (d) firing the blend to form the haloapatite phosphor. The partial substitution has been found to increase the 100-hour brightness of the haloapatite phosphors.

REFERENCES:
patent: 4446049 (1984-05-01), Pappalardo et al.
patent: 4647399 (1987-03-01), Peters et al.
Mooney et al.,Alkaline Earth Phosphates, Chemical Reviews, vol. 61, No. 5, (1961) 433-462.

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