Method of making fluoropolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Treating polymer containing material or treating a solid...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

526 89, 526245, 526247, 526251, 526942, C08F 600

Patent

active

059228334

ABSTRACT:
A process for making a fluoropolymer is disclosed. The process comprises solubilizing a fluoromonomer in solvent comprising a carbon dioxide fluid, and then polymerizing the fluoromonomer to produce a the fluoropolymer. A preferred solvent for carrying out the process is supercritical carbon dioxide; preferred fluoromonomers for carrying out the process are fluoroacrylate monomers such as 1,1-dihydroperfluorooctyl acrylate. The polymerization step is preferably carried out in the presence of an initiator such as azobisisobutyronitrile.

REFERENCES:
patent: 3294772 (1966-12-01), Cottle
patent: 3471463 (1969-10-01), Kaglya et al.
patent: 3522228 (1970-07-01), Fukui et al.
patent: 3817871 (1974-06-01), Graff
patent: 4243548 (1981-01-01), Heeb et al.
patent: 4582731 (1986-04-01), Smith
patent: 4734227 (1988-03-01), Smith
patent: 4748220 (1988-05-01), Hartmann et al.
patent: 4923720 (1990-05-01), Lee et al.
patent: 4933404 (1990-06-01), Beckman et al.
patent: 5045220 (1991-09-01), Harris et al.
patent: 5182342 (1993-01-01), Feiring et al.
patent: 5197800 (1993-03-01), Saidman et al.
patent: 5211342 (1993-05-01), Hoy et al.
patent: 5286822 (1994-02-01), Krespan et al.
patent: 5308648 (1994-05-01), Prince et al.
patent: 5310836 (1994-05-01), Treat
patent: 5330783 (1994-07-01), Saidman et al.
patent: 5345013 (1994-09-01), Van Bramer et al.
patent: 5407132 (1995-04-01), Moesserly et al.
patent: 5407267 (1995-04-01), Davis et al.
patent: 5415897 (1995-05-01), Chang et al.
patent: 5478905 (1995-12-01), Anolick et al.
V. Krukonis et al., Supercritical Fluid Chromatography Analysis of Polystyrene, Polymer Fractionation, pp. 146-147, 156-159, 244-245, 248-249.
E. Beckman et al., Phase Behavior of Inverse Microemulsions for the Polymerization of Acrylamide in Near-Critical and Supercritical Continuous Phases; J. Phys. Chem, 94 345 (1990).
S. Kumar et al., Precipitation Polymerization in Supercritical Fluids; Rolym. Prep., 27, 224 (1986).
V. Sarai et al., Free Radical Polymerization of Styrene in Supercritical Fluids; Polym. Prep, 31, 687 (1990).
K. Scholsky, Supercritical Polymerization Reactions; Polym. Prep 31, 685 (1990).
G.S. Varadarajan, Free Radical Polymerization in Supercritical Fluid Solvents (Nov. 29, 1990), (MIT Doctoral Thesis).
DeSimone et al., Dispersion Polymerizations in Supercritical Carbon Dioxide; Science 265; 356-359 (1994).
DeSimone et al., Synthesis of Fluoropolymers in Supercritical Carbon Dioxide; Science, appeared Aug. 14, 1992.
K.A. Shaffer and J.M. DeSimone; Chain Polymerization in Inert Near- and Supercritical Fluids; TRIP 3 No. 5; 146-153 (May 1995).
3M Letter dated Oct. 31, 1996.
Feiring et al., Introduction to Fluorinated Polymers Parts I and II, DuPont Experimental Station and 3M Center, 1992.
Allan T. Worm, Introduction to Fluorocarbon Elastomers, 3M Center, 1992.
Subhas V. Gangal, Tetrafluorethylene Polymers, E.I. du Pont de Nemours & Co., Inc. vol. 16, pp. 626-642, 1985.
Anestis L. Logothetis, Fluoroelastomers, Organofluorine Chemistry: Principles and Commercial Applications, 16, 1994, pp. 373-396.
Andrew E. Feiring, Fluoroplastics, Organofluorine Chemistry: Principles and Commercial Applications, 15, 1994, pp. 339-372.
Gallagher-Wetmore et al., Supercritical Fluid Processing: A New Dry Technique for Photoresist Developing, SPIE, vol. 2438, Jun. 1995, pp. 694-708.
Mawson et al., Formation of Poly(1,1,2,2-tetrahydroperfluorodecyl acrylate) Submicron Fibers and Particles from Supercritical Carbon Dioxide Solutions, Macromolecules, 1995, vol. 28, No. 9, pp. 3182-3191.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Method of making fluoropolymers does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Method of making fluoropolymers, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method of making fluoropolymers will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2276489

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.