Method of making ethylbiphenyls

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By alkyl or aryl transfer between molecules – e.g.,...

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585474, 585475, C07C 1512

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049435531

ABSTRACT:
This invention relates to a method of making ethylbiphenyls by the reaction of biphenyl with polyethylbenzenes or with ethylene and polyethylbenzenes in the presence of a solid acid catalyst and offers advantages of industrial significance such as absence of acidic waste water, no need of costly materials for equipment, catalyst reuse, and adaptability to a fixed-bed flow reaction system suitable for large-scale production.

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patent: 3410921 (1968-11-01), Pollitler
patent: 3636179 (1972-01-01), Inoue et al.
patent: 3701813 (1972-10-01), Stenmark
patent: 3716596 (1973-02-01), Bowes
patent: 3855328 (1974-12-01), Hedge
patent: 4112056 (1978-09-01), Chen
patent: 4454364 (1984-06-01), Farcasiu et al.
patent: 4547474 (1985-10-01), Olah
patent: 4642730 (1987-02-01), Sato et al.
Chemical Abstracts, vol. 108, No. 13, abstract number 111947g, 1988.

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