Method of making diammonium hydrazinium tetraperchlorate

Chemistry of inorganic compounds – Nitrogen or compound thereof – Oxygen containing

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423385, 423413, 149 75, C01B 2120, C01B 2152

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040535665

ABSTRACT:
Diammonium hydrazinium tetraperchlorate is made by reacting an ammonium compound and a hydrazinium compound preferably in a 2:1 molar ratio with perchloric acid using aqueous perchloric acid containing about 60% to 70% by weight of the acid as a reaction medium. The diammonium hydrazinium tetraperchlorate crystallizes from the solution and may be recovered therefrom by filtration, decantation or centrifuging. The tetraperchlorate formed is useful as the oxidizer component of solid rocket propellants, pyrotechnic compositions and gas generators.

REFERENCES:
patent: 3131997 (1964-05-01), Stern
patent: 3436172 (1969-04-01), Paustian et al.
patent: 3450492 (1969-06-01), Weinberg et al.
patent: 3743701 (1973-07-01), Crawford et al.
patent: 3769389 (1973-10-01), Paustian

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