Coating processes – Coating by vapor – gas – or smoke – Mixture of vapors or gases utilized
Patent
1993-02-05
1994-03-29
King, Roy V.
Coating processes
Coating by vapor, gas, or smoke
Mixture of vapors or gases utilized
4272551, 4272481, 427314, C23C 1600
Patent
active
052982874
ABSTRACT:
CVD Si.sub.3 N.sub.4 can be made by placing a substrate (2) inside a CVD reactor (4) having an interior and interior walls (6). The interior walls of the reactor are include a high temperature metal selected from the group consisting of Mo, Nb, Rh, Hf, Ta, W, Re, and Ir. An inert gas is flowed through the reactor (4) and the pressure inside the reactor is reduced to less than about 40 kPa. The substrate (2) and interior of the reactor (4) are heated to a temperature between about 1200.degree. C. and about 1700.degree. C. A reactant gas mixture of a silicon halide and an excess of a nitrogen-containing compound is flowed into the reactor such that the silicon halide reacts with the nitrogen-containing compound to form Si.sub.3 N.sub.4. The high temperature metal on the interior walls (6) of the reactor (4) inhibits the formation of Si.sub.3 N.sub.4 on the interior walls of the reactor so the majority of the Si.sub.3 N.sub.4 forms on the substrate (2).
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King Roy V.
Romanik George J.
United Technologies Corporation
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