Method of making core shell structured articles based on alumina

Glass manufacturing – Processes – With shaping of particulate material and subsequent fusing...

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65 175, 264 60, 264 62, 264 65, 501103, 501105, C03B 1901, C03B 1909, C04B 3334, C04B 3336

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056834810

ABSTRACT:
An alumina ceramic article and a method for preparing the article. The method comprises the steps of:
(1) Compacting a mixture of a first concentration of particulate aluminum oxide sufficient to prevent retention of the zirconium oxide alloy particles in the shell in a predominantly tetragonal crystal structure and a second concentration of particulate zirconium oxide alloy. The zirconium oxide alloy is zirconium oxide and a secondary oxide selected from the group consisting of MgO, CaO, Y.sub.2 O.sub.3, Sc.sub.2 O.sub.3, CeO.sub.2, and rare earth oxides having a concentration of secondary oxide generally of about 0.5 to about 5 mole percent Y.sub.2 O.sub.3, from about 0.1 to about 1 mole percent MgO, from about 0.5 to about 15 mole percent CeO.sub.2, from about 0.5 to about 7.0 mole percent Sc.sub.2 O.sub.3, or from about 0.5 to about 5 mole percent CaO, relative to the total of the zirconium oxide alloy. The compacting results in the formation of a blank.
(2) Providing contact between the blank and a dopant oxide.
(3) Sintering the blank in contact with the dopant oxide wherein said first concentration is from 50-75 weight percent of the total of the first and second concentrations.

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Introduction to Ceramics, Kingery et al, p. 64 1976.

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