Method of making chalcogen catalysts for polymer electrolyte...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Sulfur or compound containing same

Reexamination Certificate

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C429S523000, C429S524000, C429S526000

Reexamination Certificate

active

07851399

ABSTRACT:
A method of making an electrode catalyst material using aqueous solutions. The electrode catalyst material includes a support comprising at least one transition metal and at least one chalcogen disposed on a surface of the transition metal. The method includes reducing a metal powder, mixing the metal powder with an aqueous solution containing at least one inorganic compound of the chalcogen to form a mixture, and providing a reducing agent to the mixture to form nanoparticles of the electrode catalyst. The electrode catalyst may be used in a membrane electrode assembly for a fuel cell.

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patent: 2006/0105210 (2006-05-01), Surampudi et al.
Zelenay et al., “Chalcogen Catalysts for Polymer Electrolyte Fuel Cell,” U.S. Appl. No. 11/295,361, filed Dec. 5, 2005.
Alonso-Vante et al., “The Structure Analysis of the Active Center of Ru-Containing Electrocatalysts for the Oxygen Reduction. An In Situ EXAFS Study,” Electrochimica Acta 47 (2002) 3807-3814.
Solorza-Feria et al., “Novel Low-Temperature Synthesis of Semicnducting Transition Metal Chalcogenide electrocatalyst for Multielectron Charge Transfer: molecular Oxygen Reduction,” Electrochimica Acta, vol. 39, No. 11/12, pp. 1647-1653, (1994).
Malakhov, et al., “In Situ EXAFS Study to Probe Active Centers of Ru Chalcogenide Electrocatalysts During Oxygen Reduction Reaction,” J. Phys. Chem. B 2002, 106, 1670-1676.
Zhang et al., “Progress in Preparation of Non-Noble Electrocatalysts for PEM Fuel Cell Reactions,” Journal of Power Sourcesxxx(2005)xxx-xxx.

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