Method of making anhydrous lithium thiocyanate

Chemistry of inorganic compounds – Nitrogen or compound thereof – Carbon containing

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C01C 320

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042161924

ABSTRACT:
The present invention is directed to a method of making anhydrous lithium thiocyanate and solutions containing anhydrous lithium thiocyanate by reacting a thiocyanate reactant selected from the group consisting of inorganic ammonium thiocyanate, quaternary alkyl ammonium thiocyanates, trialkyl ammonium thiocyanates, non-lithium alkali metal thiocyanates and alkaline earth metal thiocyanates, with a lithium salt selected from the group consisting of LiClO.sub.4 ; LiAsF.sub.6 ; LiBF.sub.4 ; LiPF.sub.6 ; LiO.sub.3 SCF.sub.3 ; LiNO.sub.2 ; LiNO.sub.3 ; LiCl; LiBr; LiI; LiO.sub.2 CCF.sub.3 ; LiOC.sub.6 H.sub.5 ; LiB(C.sub.6 H.sub.5).sub.4 and LiBR.sub.4 wherein R is methyl, ethyl, butyl or mixtures thereof, in an organic solvent in which the reactants are soluble.

REFERENCES:
patent: 3047363 (1962-07-01), Field et al.
patent: 3049406 (1962-08-01), Grant et al.

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