Method of making a semiconductor device with aligned oxide...

Semiconductor device manufacturing: process – Making device or circuit emissive of nonelectrical signal

Reexamination Certificate

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C438S024000, C438S035000, C438S038000

Reexamination Certificate

active

06372533

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to a semiconductor device including a long-wavelength vertical cavity surface emitting laser (VCSEL) that is optically pumped by an integrated short-wavelength VCSEL, and more particularly to a process for use in fabrication of such a semiconductor device.
2. Description of the Related Art
A vertical cavity surface emitting laser (VCSEL) is a semiconductor laser including a semiconductor layer of optically active material, such as gallium arsenide or indium phosphide. The optically active material is sandwiched between mirror stacks formed of highly-reflective layers of metallic material, dielectric material, or epitaxially-grown semiconductor material. Conventionally, one of the mirror stacks is partially reflective so as to pass a portion of the coherent light which builds up in a resonating cavity formed by the mirror stacks sandwiching the active layer.
Lasing structures require optical confinement in the resonating cavity and carrier confinement in the active region to achieve efficient conversion of pumping electrons into stimulated photons through population inversion. The standing wave of reflected optical energy in the resonating cavity has a characteristic cross-section giving rise to an optical mode. A desirable optical mode is the single fundamental transverse mode, for example, the HE
11
mode of a cylindrical waveguide. A single mode signal from a VCSEL is easily coupled into an optical fiber, has low divergence, and is inherently single frequency in operation.
In order to reach the threshold for lasing, the total gain of a VCSEL must equal the total loss of the VCSEL. Unfortunately, due to the compact nature of VCSELs, the amount of gain media is limited. For efficient VCSELs, at least one of the two required mirrors must have a reflectivity greater than approximately 99.5%. It is more difficult to meet this requirement in long-wavelength VCSELs than in short-wavelength VCSELs because such high reflectivity mirrors are difficult to grow in the same epitaxial step as the long-wavelength active region. Because epitaxially-grown mirror stacks often do not enable sufficiently high reflectivity, some VCSELs are formed by wafer fusing the top and bottom mirror stacks to the active region.
Wafer fusion is a process by which materials of different lattice constant are atomically joined by applying pressure and heat to create a real physical bond. Thus, wafer fusion of one or both of the mirror stacks to the active region is used to increase the reflectivity provided by either or both of the mirrors to compensate for the small amount of gain media so that the lasing threshold can be reached and maintained.
An important requirement for low-threshold, high-efficiency VCSEL operation is a lateral refractive index variation or index guiding mechanism that introduces low optical loss for the VCSEL. Lateral oxidation of AlGaAs has been used for refractive index guiding to make high-efficiency VCSELs. In such a lateral oxidation technique, a mesa is etched into the top surface of the VCSEL wafer, and the exposed sidewalls of an AlGaAs layer are exposed to water vapor. Water vapor exposure causes conversion of the AlGaAs to AlGaO
x
, some distance in from the sidewall toward the central vertical axis, depending on the duration of oxidation. This introduces a lateral refractive index variation, creating a low-loss optical waveguide if the AlGaO
x
layer is sufficiently thin.
A long-wavelength VCSEL can be optically coupled to and optically pumped by a shorter wavelength, electrically pumped VCSEL. U.S. Pat. No. 5,513,204 to Jayaraman entitled “LONG WAVELENGTH, VERTICAL CAVITY SURFACE EMITTING LASER WITH VERTICALLY INTEGRATED OPTICAL PUMP” describes an example of a short-wavelength VCSEL optically pumping a long-wavelength VCSEL.
Two key requirements for manufacturing a long-wavelength VCSEL optically pumped by an integrated short-wavelength VCSEL are precise alignment of the optical mode of the two VCSELs over a wafer scale, combined with electrical contact to both a p-doped layer and an n-doped layer of the short-wavelength VCSEL.
This has been accomplished in the past using patterned wafer fusion to define the optical mode of the long-wavelength VCSEL, while using oxidation to define the optical mode of the short-wavelength pump VCSEL. This necessitates the difficult task of precise, sub-micron infrared photolithography over a full wafer.
SUMMARY OF THE INVENTION
The invention provides a process for use in fabrication of a semiconductor device. In the process, a short-wavelength vertical cavity surface emitting laser (VCSEL) is epitaxially grown on and integrated with a top long-wavelength distributed Bragg reflector. A long-wavelength active region is wafer fused to a bottom long-wavelength distributed Bragg reflector. The top long-wavelength distributed Bragg reflector is wafer fused to the long-wavelength active region, making a long-wavelength VCSEL beneath the short-wavelength VCSEL. The short-wavelength VCSEL includes a top oxidation layer of AlGaAs. The long-wavelength VCSEL includes a bottom oxidation layer of AlGaAs. An n-doped contact layer is interposed between the top oxidation layer of AlGaAs and the bottom oxidation layer of AlGaAs. P-type metal is deposited on a top surface of the short-wavelength VCSEL to make a p-contact of the semiconductor device. A mesa is etched in the short-wavelength VCSEL down to the n-doped contact layer, thereby forming a field around the mesa. N-type metal is deposited in the field to make an n-contact of the semiconductor device. One or more holes are patterned on top of the mesa, radially outward from the p-type metal deposit, in the shape of a non-continuous ring around the p-type metal deposit. The patterned one or more holes are etched from the top of the mesa downward through both the top oxidation layer of AlGaAs and the bottom oxidation layer of AlGaAs, and the one or more etched holes are oxidized in a single step, thereby forming a top oxide aperture in the short-wavelength VCSEL and a bottom oxide aperture in the long-wavelength VCSEL. The top oxide aperture and the bottom oxide aperture are collinear along the central vertical axis of the semiconductor device.
According to an exemplary embodiment of the invention, the fabricated semiconductor device includes a short-wavelength vertical cavity surface emitting laser (VCSEL). The short-wavelength VCSEL includes a top oxidation layer. A long-wavelength VCSEL is monolithically integrated with and optically pumped by the short-wavelength VCSEL. The long-wavelength VCSEL includes a bottom oxidation layer. A top oxide aperture is defined by the top oxidation layer, and a bottom oxide aperture is defined by the bottom oxidation layer. An n-doped contact layer is interposed between the top oxidation layer and the bottom oxidation layer. The semiconductor device presents a central vertical axis, and the top oxide aperture and the bottom oxide aperture are each centered about the central vertical axis in respective planes that are both perpendicular to the central vertical axis.


REFERENCES:
patent: 5403775 (1995-04-01), Holonyak, Jr. et al.
patent: 5513204 (1996-04-01), Jayaraman
patent: 5550081 (1996-08-01), Holonyak, Jr. et al.
patent: 5563094 (1996-10-01), Paoli et al.
patent: 5882948 (1999-03-01), Jewell
patent: 5897329 (1999-04-01), Jewell
patent: 5903588 (1999-05-01), Guenter et al.
patent: 5991326 (1999-11-01), Yuen et al.
patent: 6048748 (2000-04-01), Khare et al.
patent: 19523267 (1997-01-01), None
patent: 98/05073 (1998-02-01), None
patent: 98/31080 (1998-07-01), None
patent: 98/39824 (1998-09-01), None
Lim et al. “Sealing of Alas Against Wet Oxidation and Its Use in the Fabrication of Vertical-Cavity Surface-Emitting Lasers” American Institute of Physics 1997;71(4):1915-1917.
Lott et al., “Vertical Cavity Lasers Based on Vertically Coupled Quantum Dots,” Electronics Letters, GB, IEE Stevenage, 1997; 33(13): 1150-1151.
European Search Report EP99308774.
Oh et al. “Comparison of Vertical-Cavity S

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