Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1985-10-29
1988-06-07
Killos, Paul J.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
560185, 562579, C07C 5908, C07C 6966
Patent
active
047498110
ABSTRACT:
In the process of hydrocarboxylating an enol acylate with CO and an organic hydroxyl compound to produce an .alpha.-acyloxy acid ester, the improvement comprising using as the organic hydroxyl compound reactant, an organic hydroxyl compound which has a chiral center that is essentially all L or D, thereby producing a reaction mixture having essentially no enantiomeric pairs and containing diastereomeric .alpha.-acyloxy acid esters having two chiral centers.
REFERENCES:
patent: 2388688 (1945-11-01), Hass
patent: 4377708 (1983-03-01), Morris
Bittler, K. et al., Angew. Chem., vol. 80 (1968) pp. 352-359.
Kitamura, Takanori et al., Chemical Abstracts, vol. 98 (1983) #106,821g.
Burrington James D.
Cesa Mark C.
Dubbert Robert A.
Evans L. W.
Killos Paul J.
Lynch C. S.
The Standard Oil Company
Untener D. J.
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