Method of making a CdS/Cu.sub.x S photovoltaic cell

Metal working – Method of mechanical manufacture – Assembling or joining

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427 74, 427 87, 427 88, 148 15, H01L 3118

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044047347

ABSTRACT:
A photovoltaic cell is formed by combining a spray process, forming a crystalline layer containing cadmium and sulfur, and an evaporation process, depositing copper chloride for converting to Cu.sub.x S. The crystals containing cadmium and sulfur are heated in an atmosphere of cadmium and chlorides to obtain crystals having at least one dimension greater than 0.5 micron and a planar layer of Cu.sub.x S is formed on the large crystals. A layer of Cu.sub.x S having a thickness of 0.5-1.0 micron is obtained. Electrodes are formed from evaporated gold or chromium or a metallic paste including silver or copper. Zn.sub.x Cd.sub.1-x S may be substituted for CdS through at least part of the crystalline layer for improved Voc.

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patent: 4234353 (1980-11-01), Donaghey
A. N. Casperd et al., "Dry Barrier Formation of Cu.sub.2 S-CdS Junctions," Proceedings, Int'l Photovoltaic Solar Energy Conf., Luxembourg (1977), Reidel Pub. Co., (1978), pp. 1131-1140.
M. S. Tomar et al., "A Comparative Study of Cu.sub.2 S-Zn.sub.x Cd.sub.1-x S and Cu.sub.2 S-CdS Thin Film Solar Cells Prepared by Solid State Reaction", Jap. J. Appl. Physics, vol. 19 (1980), Supplement 19-1, pp. 567-571.
S. Martinuzzi et al., "CdZnS-CdS Bifilm Solar Photocells," Thin Solid Films, vol. 51, pp. 211-217 (1978).
L. W. Chow et al., "Cu.sub.x S/Cd.sub.y Zn.sub.1-y S and Cu.sub.x S/Cd.sub.y Zn.sub.1-y S, CdS Thin Film Solar Cells Using Chemically Sprayed Films," J. Phys. D:Appl. Phys. vol. 14, pp. 463-469 (1981).

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