Method of making 1,1'-sulfonylbis[3-nitro-5-(trifluoromethyl)ben

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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568 27, 564430, 564419, 564421, C07C31502

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active

053046820

ABSTRACT:
Disclosed is a method of making 1,1'-sulfonylbis[3-nitro-5-(trifluoromethyl) benzene] by reacting dibenzotrifluoride sulfide with at least four equivalents of fuming nitric acid and at least four equivalents of fuming sulfuric acid at a temperature below 20.degree. C., until the sulfide link is oxidized to a sulfone link, then raising the temperature to above 20.degree. C. until the reaction is complete. Also disclosed is the preparation of 1,1'-sulfonylbis[3-nitro-(5-trifluoromethyl) benzenamine] by reducing the benzene compound.

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Article by Ciocia, Canonic, G. 76[1946] 113, 116 (Abstract).
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