Method of liquefaction of carbonaceous materials

Mineral oils: processes and products – Products and compositions – Lubricating oils

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208 8LE, 201 25, 585240, 568761, C10G 106, C10G 100, C10B 4300, C07C 100

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active

044513518

ABSTRACT:
Hydrocarbon liquids are obtained from carbonaceous materials, such as coal, by contacting the carbonaceous materials with a metal carbonyl or a low valent complex of the transition metals and water gas under alkaline conditions to form a reaction mixture, and then heating the reaction mixture to a sufficient temperature and pressure to obtain the hydrocarbon liquids. In a second embodiment, the carbonaceous materials are solubilized to an unexpectedly high degree by contacting them with solvent/solute systems, such as phenolic recycle solvents containing alkali or alkaline-earth metal constituents.

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Solvation and Hydrogenation of Coal, Orchin et al., Industrial and Engineering Chemistry, vol. 40, No. 8, 8/48, pp. 1385-1389.

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