Fabric (woven – knitted – or nonwoven textile or cloth – etc.) – Woven fabric – Including a free metal or alloy constituent
Reexamination Certificate
2000-01-28
2003-01-28
Morris, Terrel (Department: 1771)
Fabric (woven, knitted, or nonwoven textile or cloth, etc.)
Woven fabric
Including a free metal or alloy constituent
C427S250000, C427S265000, C427S288000, C427S404000, C427S383100, C427S389900, C442S148000, C442S152000, C442S153000, C442S164000, C442S228000
Reexamination Certificate
active
06511929
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to metallized, particularly aluminized, fabrics which are coated with specific polyurethane finishes. Such specific polyurethanes must be cross-linked and present in latex form. Upon impregnation within metal-coated fabrics, these particular polyurethanes provide vastly improved washfastness properties to the fabrics and thus ensure the retention of substantially all the metal coating within and on the target fabric.
DISCUSSION OF THE PRIOR ART
Metallized fabrics have recently been utilized in order to provide effective heat insulation for garments, particularly apparel for use outdoors and in cold-weather climates. Other uses for such fabrics have included incorporation within radar-detectable objects, such as in U.S. Pat. No. 4,390,588, to Ebneth et al.; water-repellent automobile covers, as in U.S. Pat. No. 5,271,998, to Duckett et al.; strength-enhanced fibrous materials, as in U.S. Pat. No. 3,660,138, to Gorrell. Washfastness is a very important characteristic which needs to be exhibited by metallized fabrics, particularly those which are intended to be incorporated within garments. Generally, such metal coatings, in particular aluminum, easily washes out of and from fabric substrates upon standard laundering procedures. Past attempts have been made to reduce the loss of metal from such fabrics. These include U.S. Pat. No. 5,744,405, to Okumura et al., which requires a siloxane over coat adhered to the metal-coated fabric through a plasma pre-treatment; and U.K. Patent 800,093, to Kunsch, which discloses the pre-treatment of fabric with cross-linked polyurethanes and the like, prior to depositing metal on the treated fabric surface. The Kunsch pre-treatment basically acts as an adhesive for the metal to remain bonded to the fabric substrate. These methods have proven to be either costly (with the high expense of plasma pre-treatments and particular siloxanes), or ineffective (with the mere utilization of an adhesive to bind the metal to the fabric leaving an appreciable amount of metal susceptible to removal through inadvertent contact and friction with certain surfaces as well as corrosion through atmospheric and aqueous oxidation). As such, there is no teaching or fair suggestion within the prior art which pertains to the improvement in metal-coated fabric washfastness provided by cross-linked polyurethane/acrylic polymer which is impregnated within the target fabric after deposition of the metal composition.
DESCRIPTION OF THE INVENTION
It is thus an object of the invention to provide improved washfastness for metallized fabrics. A further object of the invention is to manufacture a polyurethane-coated, aluminized fabric with better washfastness than comparable aluminized fabric. Another object of the invention is to provide a metallized fabric for incorporation within garments for the outdoor and cold-weather climate apparel industries which provides effective and appreciable levels of heat insulation throughout the wearable lives of such garments. Yet another object of this invention is to provide a fabric for use in any type of heat insulation covering or fabric and not necessarily within apparel. Still a further object of the invention is to provide a method for producing such a metallized, washfast, heat insulation fabric.
Accordingly, this invention encompasses a fabric comprising a metal coating wherein said metal coating comprises discrete metal particles which are encapsulated within a cross-linked polyurethane latex. Nowhere within the prior art has such a specific encapsulated metal coating for fabrics been utilized to impede corrosion of the metal particles adhered to the fabric surface thereby substantially eliminating the removal of such metal particles from the fabric substrate due to atmospheric conditions and/or harsh laundering conditions.
Any fabric can be utilized in this invention as the important requirement is that the polyurethane latex thoroughly coat the metal particulate coating of the fabric in such a way as to substantially prevent contact between the metal and atmospheric oxygen or harsh oxidizing (and thus corrosive) chemicals present within laundry applications. Polyester is most preferred; however, any natural fibers, such as cotton, ramie, and the like; any synthetic fibers, such as polyamides, lycra, and the like; and any blends thereof of any natural and/or synthetic fibers may be utilized within the inventive fabric. Furthermore, woven fabrics are preferred; however, knitted and non-woven forms may also be utilized as well as combinations of any types of these forms. The important limitation of this invention is the presence of the polyurethane latex over the metal coating of the target fabric to provide a barrier to corrosive elements and thus ultimately provide a long-lasting fabric for the retention of heat.
Any metal generally utilized within a coating for fabrics may be utilized within this invention, also. The most common metal for this purpose, aluminum, is most preferred, basically because of its low cost in combination with its superior performance (particularly in provided heat retention for clothing in cold climates). Other metals which may be utilized include copper, silver, nickel, zinc, titanium, vanadium, and the like.
The preferred polyurethane component is a waterborne aliphatic or aromatic polymer which also lends a soft hand to the target fabric. As such, the preferred polyurethane is a dispersion comprising a polyurethane having an elongation of at least 150% and conversely a tensile strength at most 7,000 psi. Particular examples of such dispersions include those within the Witcobond® polyurethane series, from Witco, such as W-232, W-234, W-160, W-213, W-236, W-252, W-290H, W-293, W-320, and W-506; most preferred is W-293. Acrylic polyurethane dispersions may also be utilized provided they exhibit the same required degree of elongation and tensile strength as for the purely polyurethane dispersions.
Any cross-linking agent compatible with polyurethanes may be utilized within this invention, particularly those which have low amounts of free formaldehyde. Preferred as cross-linking agents are Cytec™ M3 and Aerotex™ PFK, both available from BFGoodrich. Any catalyst, which is generally necessary to initiate and effectuate cross-linking of a polyurethane dispersion, which is compatible with both a polyurethane and a polyurethane cross-linking agent maybe utilized within this invention. Preferred as a cross-linking catalyst is Cytec™ MX, available from BFGoodrich.
The cross-linked polyurethane latex of the invention may be present in any amount and concentration within an aqueous solution for use on and within the target fabric. The table below indicates the difference in performance of the cross-linked polyurethane latex in reference to its concentration and dry solids addition rate on the fabric surface. Preferably, the concentration of the polyurethane is from 5 to 100% by weight of the utilized aqueous solution; more preferably from 10 to about 75% by weight; and most preferably from 25 to about 50% by weight. The coating addition rate (measured as the percent of dry solids addition on the weight of the fabric) of the cross-linked polyurethane dispersion is preferably from 3 to 50% owf; more preferably from about 6 to about 40% owf; and most preferably from about 15 to about 30% owf.
As noted below, the basic procedure followed in applying this cross-linked polyurethane dispersion entails first providing a metal-coated fabric. Next, the latex is formed by combining the polyurethane with the cross-linking agent and optionally a catalyst to effectuate such cross-linking of the polyurethane. The resultant latex is then diluted with water to the desired concentration which will provide the most beneficial washfastness of the metal coating after treatment. The metal-coated fabric is then saturated with the resultant aqueous solution of the polyurethane latex with the excess being removed. Such saturation and removal of the latex may be performed in any standard manner, inc
Kanipe Tina Louise
Vogt Kirkland W.
Guarriello John J.
Milliken & Company
Morris Terrel
Moyer Terry T.
Parks William S.
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