Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing
Patent
1998-01-05
1999-08-24
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Silicon containing
556459, 556461, 556415, 556419, 549215, 540487, 528 9, 528 10, 528 15, 528 19, C07F 708
Patent
active
059426381
ABSTRACT:
A synthetic process for the selective preparation of reactive polyhedral oligomeric silsesquioxanes (POSS) as well as polyhedral oligomeric silicate (POS) (spherosilicate) is provided. The method claimed herein employs metal catalyzed metathesis reactions for the selective reaction of .alpha.-olefin containing polyhedral oligomeric silsesquioxanes or silicates with olefinic reagents bearing functionalities useful for grafting reactions, polymerization chemistry and sol-gel processes. The use of metal catalyzed metathesis chemistry to form both linear or network polyhedral silsesquioxane polymers directly from .alpha.-olefin-containing polyhedral oligomeric silsesquioxanes is also described.
REFERENCES:
patent: 5484867 (1996-01-01), Lichtenhan et al.
patent: 5589562 (1996-12-01), Lichtenhan et al.
Feher Frank J.
Lichtenhan Joseph D.
Schwabb Joseph J.
Soulivong Daravong
Shaver Paul F.
Stover Thomas C.
The United States of America as represented by the Secretary of
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