Method of forming poly-(3-substituted) thiophenes

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From sulfur-containing reactant

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528373, 528378, 528379, 524418, 524609, 526256, C08G 7500, C08F 2806

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061661724

ABSTRACT:
A method of forming a regioregular polythiophene from a polymerization reaction is described. The method proceeds by combining a soluble thiophene having at least two leaving groups with an organomagnesium reagent to form a regiochemical isomer intermediate, and adding thereto an effective amount of Ni(II) catalyst to initiate the polymerization reaction.

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