Method of forming high purity metal silicides targets for sputte

Plastic and nonmetallic article shaping or treating: processes – Gas or vapor deposition of article forming material onto...

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4272552, 20419217, 20429812, 20429813, C23C 1642, C23C 1440, C23C 1416

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active

050552465

ABSTRACT:
The invention relates to a process of making a high purity silicide target comprising the steps of providing a substrate in a CVD enclosure, evacuating said enclosure up to a pressure P1 which is at least equal to or smaller than 5.times.10.sup.-5 Torr, heating the substrate at a temperature T1, which is at least equal to or greater than 20.degree. C., injecting in said enclosure a refractory metal halide MXm having a purity, as far as metallic impurities are concerned, greater than 5N (99,999%) and a silicon hydride having a purity, as far as metallic impurities are concerned, greater than 6N (99,9999%) setting the pressure in the enclosure between about 0.01 Torr and the atmospheric pressure while maintaining the temperature in the CVD enclosure between about 20.degree. C., growing a refractory metal silicide layer on the substrate to make a target having a purity, as far as metallic impurities are concerned, greater than 5N (99,99%), maintaining the temperature in the enclosure during said growing step at a value T2 which is not greater than T1, then withdrawing the target from said CVD enclosure.

REFERENCES:
patent: 4750932 (1988-06-01), Parent et al.
patent: 4851295 (1989-07-01), Brors
patent: 4938798 (1990-07-01), Chiba et al.

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