Method of forming built-up film of fluorinated aliphatic compoun

Coating processes – Applying superposed diverse coating or coating a coated base – Synthetic resin coating

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264298, 4273855, 4273935, 4273936, 4274301, 4274432, B05D 136

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046968385

ABSTRACT:
Using the Langmuir-Blodgett's technique and a compound represented by the general formula CF.sub.3 (CF.sub.2).sub.n (CH.sub.2).sub.m --X, wherein X is a hydrophilic group, preferably --COOH, n is from 5 to 20 and m is from 0 to 10, a firm built-up film having a desired number of monomolecular layers can surely be formed on a solid substrate surface by spreading a monomolecular film of the fluorinated compound on an aqueous phase containing trivalent metal ions. In the obtained built-up film the CF.sub.3 -terminated molecules are well oriented in the direction of the thickness of the film. The built-up film fully exhibits extreme hydrophobicity, high insulation, low refraction and other properties characteristic of the fluorine-containing compound.

REFERENCES:
patent: 4276350 (1981-06-01), Franz
patent: 4311764 (1982-01-01), Franz
John H. Clint et al, Interaction Energies Between Layers of Alkyl and Partially Fluorinated Alkyl Chains in Langmuir-Blodgett Multilayers, Journal of Colloid and Interface Science, vol. 47, No. 1, Apr. 1974, pp. 172-185.

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