Method of forming a single crystal film of sodium-beta "-alumina

Single-crystal – oriented-crystal – and epitaxy growth processes; – Forming from vapor or gaseous state – With decomposition of a precursor

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117 84, 117 88, C30B 2508

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active

054151279

ABSTRACT:
Disclosed herein is a method of forming a single crystal film of sodium-beta"-alumina, comprising the steps of providing a single crystal substrate with one surface being arranged to minimize nucleation sites thereon, at least a portion of the substrate including alumina. A single crystal substrate is then deposited in a chamber, along with a precursor in the chamber. The precursor has a sufficient quantity of sodium species in a vapor phase and at an energy level sufficient to react with the alumina to form sodium-beta"-alumina. The precursor also includes a sufficient quantity of a stabilizing ion with a valence equal to or lower than aluminum to minimize decomposition of sodium-beta"-alumina to sodium-beta-alumina.

REFERENCES:
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patent: 4052538 (1977-10-01), Eddy et al.
patent: 4244986 (1981-01-01), Paruso
patent: 4375701 (1983-02-01), Singh
patent: 4381216 (1983-04-01), Singh
patent: 4381968 (1983-05-01), Singh
patent: 4664849 (1987-05-01), Farrington
patent: 4732741 (1988-03-01), Duncan
patent: 4792377 (1988-12-01), Dunn
patent: 4797269 (1989-01-01), Bauer
patent: 4946664 (1990-08-01), Van Zyl
Chemical Abstracts vol. 107, 1987 No. 124803.

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