Method of forming a self-aligned contact, and method of...

Semiconductor device manufacturing: process – Chemical etching – Having liquid and vapor etching steps

Reexamination Certificate

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Details

C438S725000, C438S692000, C438S239000, C438S241000, C438S250000, C438S253000

Reexamination Certificate

active

06777341

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method of fabricating a semiconductor device. More particularly, the present invention relates to a technique of forming a self-aligned contact, and to a method of fabricating a semiconductor device having a self-aligned contact formed by such a technique.
2. Description of the Related Art
As semiconductor devices become smaller and smaller, the line width and the spacing between lines of the devices decrease. The resolution of a lithographic process used to form the lines of the semiconductor device must be increased to provide a smaller line width and spacing. However, the precision of an alignment technique, carried out to facilitate the lithographic process, can not be increased to comport with the increased resolution used to produce the fine line width and line spacing demanded of today'semiconductor devices. Accordingly, any misalignment during the fabrication of semiconductor must be minimized if a reduction in the size of semiconductor devices is to be achieved.
In the case of a semiconductor memory device, such as a dynamic random access memory (DRAM) including a capacitor, the capacitor is formed after a bit line is formed. A buried contact (BC) pad for electrically connecting the source/drain region of a transistor to the storage electrode of the capacitor is formed after the bit line is formed. A long and deep contact hole, i.e., a contact hole having a high aspect ratio, is required to form the BC pad. However, it is not easy to secure an alignment margin sufficient for a lithographic process to produce a contact hole having a high enough aspect ratio. In particular, an alignment margin can not be secured for a design rule of 0.20 &mgr;m or smaller.
Recently, a technique of forming a self-aligned contact hole has been mainly used in connection with the forming of a BC pad. In this technique, a contact hole is formed by depositing an insulation layer on a lower conductive layer, and performing an etching process using the lower conductive layer and the insulation layer as a mask. This method will be described below with reference to
FIGS. 1-5
.
FIG. 1
shows the layout of a photoresist layer pattern used as an etching mask in the conventional method of forming a self-aligned contact.
FIGS. 2 through 5
are sectional views taken along the line I-I′ of FIG.
1
and show the progression of the conventional method of forming a self-aligned contact.
In
FIG. 1
, reference numeral
100
denotes an active mask window for defining an active region and a field region. Reference numeral
110
denotes a gate mask window used for forming a gate stack pattern. Reference numeral
120
denotes a bit line mask window used for forming a bit line pattern. Reference numeral
130
denotes a photoresist layer pattern serving as an etching mask used for forming a self-aligned contact hole.
Referring to
FIG. 2
, isolation regions
210
defining active regions
205
are formed as trenches in a semiconductor substrate
200
using the active mask windows (
100
in FIG.
1
). A conductive film pad
220
is formed on each of the active region
205
. A first interlayer insulation layer
230
is formed to completely cover the conductive film pads
220
. Next, bit line stacks
240
are formed on the first interlayer insulation layer
230
using the bit line mask windows (
120
in FIG.
1
). Each of the bit line stacks
240
is formed by sequentially forming a barrier metal layer
241
, a bit line conductive layer
242
and a bit line capping layer
243
one upon the other. Subsequently, bit line spacers
250
are formed on the sidewalls of each of the bit line stacks
240
.
Referring to
FIG. 3
, a second interlayer insulation layer
260
is formed to completely cover the bit line stacks
240
and the bit line spacers
250
. Subsequently, the second interlayer insulation layer
260
is planarized such that the second interlayer insulation layer
260
has a predetermined thickness at the bit line stacks
250
.
Referring to
FIG. 4
, a photoresist film pattern
130
is formed on the second interlayer insulation layer
260
. The photoresist film pattern
130
is formed such that only those portions of the second interlayer insulation layer
260
between the bit line stacks
240
are exposed, and the remaining portions of the second interlayer insulation layer
260
are covered, as is also well shown in FIG.
1
. After the photoresist film pattern
130
is formed, the second interlayer insulation layer
260
and the first interlayer insulation layer
230
are etched using the photoresist film pattern
130
as an etching mask. As a result, contact holes
270
exposing the top surfaces of the conductive film pads
220
are formed, as shown in FIG.
5
. Conductive plugs (not shown) can be formed by filling the contact holes
270
with conductive material.
As the integration density of semiconductor devices increases, it becomes more difficult to etch the insulation layers to form the contact holes
270
due to the accumulation of polymer. Thus, the amount of polymer generated during the etching process must be somehow limited to prevent the etching process from stopping prematurely. However, reducing the amount of polymer that will be generated is accompanied by a reduction in the selection ratio with respect to the bit line spacers
250
formed of silicon nitride. Therefore, when this countermeasure is taken, the bit line spacers
250
will be etched when the mask
130
is even slightly misaligned. When the bit line spacers
250
are over-etched, the bit line conductive layer
242
may be exposed, as shown at part A in FIG.
5
. As a result, the conductive plug filling the contact hole will directly contact the bit line conductive layer
242
, whereby the lower electrode of a capacitor and the bit line are short-circuited.
SUMMARY OF THE INVENTION
A first object of the present invention is to solve the above-described problems by providing a method of forming a self-aligned contact characterized by an alignment margin sufficient to prevent a short from being created between adjacent conductive layers.
To achieve this object, the present invention provides a method in which gate stacks are formed in a striped pattern on a semiconductor substrate, gate spacers are formed on the sidewalls of the gate stacks, conductive film pads serving as buried contact pads are formed between the gate spacers, a first interlayer insulation layer is formed on the conductive film pads and the gate stacks, bit line stacks are formed on the first interlayer insulation layer in a striped pattern extending crosswise relative to the striped pattern of the gate stacks, bit line spacers are formed on the sidewalls of the bit line stacks, a second interlayer insulation layer is formed on the first interlayer insulation layer in such a way that the upper surfaces of the bit line stacks are exposed, and a photoresist film pattern is formed on the second interlayer insulation layer in a striped pattern parallel to the striped pattern of the gate stacks. The photoresist film pattern exposes segments of the bit line stacks and portions of the second interlayer insulation layer disposed directly above respective ones of the conductive film pads. Contact holes exposing the conductive film pads are formed by etching the second interlayer insulation layer and the first interlayer insulation layer using the photoresist film pattern, the bit line stacks and the bit line spacers as etching masks. The conductive plugs contacting the conductive film pads are formed by filling the contact holes with a conductive material.
Preferably, each of the gate stacks includes a gate insulation layer, a gate conductive layer and a gate capping layer which are sequentially formed one atop the other on the semiconductor substrate, and each of the bit line stacks includes a barrier metal layer, a bit line conductive layer and a bit line capping layer which are sequentially formed one atop the other on the first interlayer insulation layer.
The second int

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