Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...
Patent
1985-06-06
1987-10-06
Ziegler, Jacob
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Mixing of two or more solid polymers; mixing of solid...
525 93, 525 97, 525 99, C08L 5300
Patent
active
046983899
ABSTRACT:
A process for the production of a nonaqueous stable emulsion feedstock comprising a rubber, a block copolymer having at least one component miscible with the rubber and at least one component miscible with the monomer, and at least two unsaturated organic monomers capable of free radical polymerization is disclosed. At least one of the monomers must be miscible with the rubber and the mixture of the monomers is substantially a nonsolvent for the rubber. The block copolymer maintains the rubber or rubber-rich particles in emulsified form within the mixture of monomers. In general, the process comprises (1) mixing the rubber, block copolymer and at least a portion of the rubber miscible monomers to form a first nonaqueous solution, (2) mixing the remaining monomers and the remaining portion of the rubber miscible monomers to form a second solution, and (3) combining the two solutions to form the nonaqueous stable emulsion feedstock. A process for polymerizing this feedstock material and the polymerization product produced thereby is also disclosed.
REFERENCES:
patent: 4469844 (1984-09-01), Doak
patent: 4469845 (1984-09-01), Doak
Quigley Vincent P.
Shyu Wen B.
Woodhead David A.
Evans Larry W.
Miller John E.
The Standard Oil Company
Yusko David P.
Ziegler Jacob
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