Radiation imagery chemistry: process – composition – or product th – Visible imaging including step of firing or sintering
Reexamination Certificate
2001-12-28
2004-02-17
McPherson, John A. (Department: 1756)
Radiation imagery chemistry: process, composition, or product th
Visible imaging including step of firing or sintering
C430S321000, C445S024000
Reexamination Certificate
active
06692885
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method of fabricating barrier ribs in a plasma display panel enabling to form barrier ribs of high precision and resolution for a large screen using photosensitive glass powder.
2. Background of the Related Art
Generally, a plasma display panel (hereinafter abbreviated PDP) is manufactured by arranging cathode and anode electrodes between a pair of glass substrates confronting each other to cross each other, injecting a discharge gas between the substrates, and sealing the substrates. PDP displays a predetermined image by applying a predetermined voltage between the cathode and anode electrodes so as to bring about gas discharge at a crossing of the electrodes. PDP has been used for a monitor of OA appliance. Lately, many efforts are made to apply PDP to the wall-hanging TV and the next generation HDTV and the like with colorization. Compared to LCD, PDP provides a large-scaled screen with ease so as to expand to be applied to various fields such as various displays and the like.
FIG. 1
illustrates an AC type PDP which is widely produced.
Referring to
FIG. 1
, PDP includes a pair of glass substrates. In this case, a front glass substrate is called a front substrate and the other glass substrate at the rear of the front substrate is called a rear substrate
2
.
On the front substrate
1
of the AC type PDP, formed are transparent electrodes
3
for discharge and bus electrodes (attached to the transparent electrodes) to reduce line resistance of the transparent electrodes
3
by bringing about discharge opposite to the transparent electrodes
3
.
And, a transparent dielectric layer
4
and a protecting layer
5
to protect the electrodes are formed on the front substrate
1
. The protecting layer
5
maintains a discharge state by releasing electrons during discharge so as to control an excessive discharge current. On the rear substrate
2
, barrier ribs
7
as partition walls to provide discharge spaces are formed like stripes over data electrodes
6
for writing. Inside each of the discharge spaces, fluorescent layers
8
of RGB three colors are arranged regularly for luminescence and colorization of visible rays.
The front and rear substrates
2
are bonded together by a seal layer. After maintaining a vacuum state between the substrates, a gas is injected between the bonded glass substrates so as to generate ultraviolet rays during discharge. A mixed gas such as He+Xe or Ne+Xe is mainly used for the injected gas. Modules such as driver IC and the like are installed at the above structure, thereby completing the AC type PDP.
In the AC type PDP, the barrier ribs
7
secures discharge spaces, prevents the 3-colored fluorescent layers
3
from being mixed each other, and prevents electric and optical crosstalk between discharge cells. Therefore, the barrier ribs
8
become an important factor to increase display quality and luminescence efficiency. As a panel requires large scale and high precision & resolution, many efforts are made to study the barrier ribs.
In order to fabricate the barrier ribs, there are screen printing, sand blasting, additive method, LTCCM (low temperature cofired ceramic on metal) which is used embossing, and the like.
Screen printing carries out the steps of screen-printing a rib material and drying the printed rib material
8
to
10
times so as to stack the rib material up to a designed height. After printing the rib material, a next layer is printed thereon during a natural drying process before the previously printed rib material fails to be dried up. Thus, it is very important haw far the printed rib material runs dry. Screen printing has advantages such that a screen printer is not expensive and that the material is not wasted. Namely, the rib material is printed on the designed spots only. Yet, it is very difficult to make the heights of the respective ribs uniform due to a number of printings. Besides, the pattern of the ribs fails to meet the requirement of the product such as high precision and fine resolution.
Originally, sand blasting is used for engraving letters on a tombstone or sculpturing a glass, in which sands are jetted on a stone so that the frictional energy of the sands carves the stone. Sand blasting enables to form a micro pattern using photolithography as well as form the ribs on a large-scaled substrate. Yet, sand blasting fails to prevent cracks in the glass substrate due to the impact of an abradant thereon.
In the additive method, a photoresist film is attached on a glass substrate, and exposure and development are carried out on the photoresist film so as to leave portions of the film between patterns which will become the ribs. A rib material charges the spaces and runs dry. After removing the photoresist film, the rib material is plasticized so as to complete the ribs. Such an additive method requires no sand blaster, thereby preventing massive dusts. And, the additive method is suitable for forming the ribs on a large-scaled substrate. Yet, the additive method has difficulty in separating the photoresist from a glass paste so as to leave residues. Besides, the barrier ribs may collapse during formation.
And, compared to other methods, LTCCM has a simple process.
FIG. 2A
to
FIG. 2H
illustrate a process of fabricating barrier ribs using LTCCM.
Referring to
FIG. 2A
, a green sheet
30
is prepared. The green sheet
30
is prepared by putting a slurry, which is formed by mixing glass powder, organic solvent, plasticizer, binder, additive and the like together with a predetermined ratio, on a polyester film, forming the slurry as a sheet figure by doctor blade, and carrying out a drying process thereon. A substrate
32
to which the green sheet
30
is bonded is formed of metal such as titanium. Titanium is superior to glass or ceramic material in degree of strength and thermal resistance, thereby enabling to be prepared thinner than the glass or ceramic materials as well as reduce thermal and mechanical distortion.
Referring to
FIG. 2C
, glass powder, which is grinded finely and dried, is sprayed on the metal substrate
32
and dried before bonding the substrate
32
and green sheet
30
together so as to ease the conjunction between the metal substrate
32
and green sheet
30
. The sprayed fine glass powder is melted to be adsorbed on a surface of the substrate
32
by heat treatment at 500 to 600° C.
Referring to
FIG. 2C
, the green sheet
30
is bonded to the substrate
32
, on which the glass powder is adsorbed, by lamination.
Referring to
FIG. 2D
, address electrodes
2
are patterned on the green sheet
30
. The green sheet
30
is then dried.
Referring to
FIG. 2E
, dielectric slurry is printed on the substrate
30
on which the address electrodes
2
have been formed. And, the dielectric slurry is dried. Thus, an electrode passivation layer
36
is formed. After the formation of the electrode passivation layer
36
, a second laminating is carried out so as to increase adhesiveness between the electrode passivation layer
36
and the green sheet
30
having the address electrodes
2
.
In order to increase liquidity of the green sheet
30
bonded to the substrate
32
, the substrate is heated at a temperature below a softening point of the organic material used as a binder.
Referring to
FIG. 2F
, the green sheet
30
of which liquidity is increased is aligned on a metallic pattern
38
having grooves
38
a
which have counter-figures of barrier ribs to be formed.
Referring to
FIG. 2G
, the metallic pattern
38
is pressed by a pressure over 150 Kgf/cm
2
so that the green sheet
30
and electrode passivation layer
36
fill the grooves
38
a
of the metallic pattern
38
.
Referring to
FIG. 2H
, the metallic patter
38
is separated from the green sheet
30
and electrode passivation layer
36
. Barrier ribs are then formed through heating-maintaining-cooling steps.
LTCCM has an advantage of forming the barrier ribs with ease. Yet, LTCCM has difficulty in selecting a composition of a green sheet enabling t
Lee Hong Degerman Kang & Schmadeka
LG Electronics Inc.
McPherson John A.
LandOfFree
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